國立臺南大學專任教師基本資料
姓名蒲盈志
系所材料科學系
職稱助理教授
校內分機665
EMAILycpu@mail.nutn.edu.tw
辦公室格致樓 506B
網址https://scholar.google.com.tw/citations?userkVwZrp0AAAAJ&hlzh-TW
專長/研究領域一維奈米異質結構, 超快雷射光譜,載子動力學,再生能源應用
學位畢業學校國別主修學門修業期間
學士國立中興大學台灣化學系2000/09~2004/06
碩士國立成功大學台灣化學所2004/09~2006/07
博士國立交通大學台灣材料科學與工程所2008/09~2014/01
服務機關部門系所職稱服務期間
工業技術研究院材料與化學工程所副研究員2006/10~2012/07
美國加州大學 聖塔克魯茲分校化學與生物化學系訪問學者(科技部千里馬計畫)2012/08~2013/08
美國加州大學 聖塔克魯茲分校化學與生物化學系博士後研究員2014/02~2015/07
著作名稱:Dependence of Interfacial Charge Transfer on Bifunctional Aromatic Molecular Linkers in CdSe Quantum Dot Sensitized TiO2 Photoelectrodes. ACS Appl. Energy Mater., 2018, 1, 2907-2917
年度:2018
類別:期刊論文
摘要:Quantum dot (QD) sensitization of TiO2 is a powerful method to improve its performance as a photoanode material in solar energy conversion. The efficiency of sensitization depends strongly on the rate of interfacial electron transfer (ET) from the QDs to TiO2. To understand the key factors affecting the ET, arene-substituted (ortho, meta, and para) bifunctional linkers with single or double aromatic rings were employed to link CdSe QDs to TiO2 and control the strength of their interaction as well as the rate of interfacial ET. Interestingly, the para-substituted aromatic linker, 4-mercaptobenzoic acid (4MBA) with the longest distance between the carboxyl and thiol groups, shows the best photoelectrochemical (PEC) performance, when compared to those of ortho-subtituted (2-mercaptobenzoic acid, 2MBA) and meta-substituted (3-mercaptobenzoic acid, 3MBA) aromatic linkers. Two other bifunctional linkers with double aromatic rings, 4′-mercapto-[1,1′-biphenyl]-4-carboxylic acid (4M1B4A) and 6-mercapto-2-naphthioc acid (6M2NA), were also studied for comparison. Ultrafast transient absorption (TA) spectroscopy was used to study the exciton dynamics in CdSe QDs and determine the interfacial ET rate constant (kET). The kET results are consistent with the trend of PEC measurements in that 4MBA shows the highest kET. To gain further insight into the ET mechanism, we performed density functional theory (DFT) calculations to examine the intrinsic properties of the linkers. The results revealed that the favorable wave function distribution of the molecular orbitals of 4MBA and 4M1B4A are responsible for the higher interfacial ET rate and PEC performance due to better interfacial coupling, a factor that dominates over distance. The present study provides important new insight into the mechanism of interfacial ET using aromatic bifunctional linkers, which is useful in designing QD sensitized semiconductor metal oxide nanostructures for applications including photovoltaics and solar fuel generation.
關鍵字:bifunctional linker; CdSe; density functional theory; electron transfer; PEC; quantum dot; TiO2; transient absorption
著作名稱:Photophysical Properties and Improved Stability of Organic–Inorganic Perovskite by Surface Passivation. J. Phys. Chem. C, 2018, 122, 15799–15818. [SCI IF: 4.484]
年度:2018
類別:期刊論文
摘要:Organic–inorganic perovskite materials in the form of nanocrystals and thin films have received enormous attention recently because of their unique optoelectronic properties such as high absorption coefficient, narrow and tunable emission bandwidth, high photoluminescence quantum yield, long exciton lifetime, and balanced charge transport properties. These properties have found applications in a number of important fields, including photovoltaic solar cells, light-emitting diodes, photodetectors, sensors, and lasers. However, the stability of the materials and devices is strongly affected by several factors such as water moisture, light, oxygen, temperature, solvent, and other materials in contact such as metal oxides used in devices. Defects, particularly those related to surface states, play a critical role in the stability as well as the performance of the perovskites. Various surface modification and defect passivation strategies have been developed to enhance stability and improve performance. We review some recent progress in the development of synthetic approaches to produce high-quality nanostructured and bulk film perovskites with controlled properties and functionalities. We also highlight the degradation mechanism and surface passivation approaches to address the issue of instability. To help gain deeper fundamental insight into mechanisms behind degradation and surface passivation, relevant properties, including structural, optical, electronic, and dynamic, are discussed and illustrated with proposed models.
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著作名稱:Au–Cd1−xZnxS core–alloyed shell nanocrystals: boosting the interfacial charge dynamics by adjusting the shell composition. J. Mater. Chem. A, 2018, 6, 17503-17513. [SCI IF: 9.931]
年度:2018
類別:期刊論文
摘要:Au–Cd1−xZnxS core–shell nanocrystals (NCs) with controllable shell compositions (from x 0 to x 0.37) were synthesized by using the hot-injection method. By increasing the mole fraction of ZnS in the Cd1−xZnxS shell, the conduction band of Cd1−xZnxS can be cathodically shifted to cause an increase of energy difference between the conduction band level of the Cd1−xZnxS shell and the Fermi level of the Au core, thereby enlarging the driving force of interfacial electron transfer to enhance the photoelectrochemical (PEC) efficiency. The interfacial charge dynamics of the samples were examined by time-resolved photoluminescence (TRPL) spectroscopy. The results showed that the interfacial electron transfer rate constant (ket) from the Cd1−xZnxS shell to the Au core was increased by 2 orders of magnitude, from 2.41 × 107 to 4.91 × 109 s−1 as the mole fraction of ZnS increased from 0 to 0.37. Furthermore, PEC characterization, including Mott–Schottky analysis and photovoltage decay measurements, illustrated that gradually introducing ZnS into the shell composition of Au–Cd1−xZnxS NCs can modify the band structure and enhance the effectiveness of interfacial ET for advancing the PEC properties. The practical use of Au–Cd1−xZnxS NCs in PEC methanol oxidation was also demonstrated, revealing their promising potential as viable photoelectrodes for various PEC applications. The present study delivers an alternative approach of modulating the interfacial ET dynamics of core–shell MSNs by means of shell composition adjustment. The illustrations provide an empirical guideline to the intelligent design of core–shell metal–semiconductor nanoheterostructures (MSNs) for the desired PEC applications.
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著作名稱:Methylamine lead bromide perovskite/protonated graphitic carbon nitride nanocomposites: interfacial charge carrier dynamics and photocatalysis, J. Mater. Chem. A, 2017, 5, 25438–25449. [SCI IF: 9.931]
年度:2017
類別:期刊論文
摘要:We demonstrate the decoration of methylamine lead bromide (MAPbBr3, MA: CH3NH3 +) perovskite nanoparticles on protonated graphitic carbon nitride (p-g-C3N4) sheets to form nanocomposites (NCs) for the first time. The intrinsic type II band structure of MAPbBr3/p-g-C3N4 NCs resulted in significant charge separation properties, which were greatly beneficial for related applications in photoelectric conversion. The interfacial charge transfer behavior of MAPbBr3/p-g-C3N4 NCs was analyzed via timeresolved photoluminescence (TRPL) spectroscopy and singular-value decomposition global fitting (SVD-GF), which revealed that photoexcited electrons in the conduction band (CB) and shallow-trap (ST) states of MAPbBr3 could be transferred into the CB of g-C3N4. The fitting results for TRPL traces indicated that the control of the related compositions could modulate the interfacial charge carrier dynamics of MAPbBr3/g-C3N4 NCs. An increase in the charge transfer rate constant (ket) for MAPbBr3/g- C3N4 NCs was discovered when the constituent ratio of p-g-C3N4 was enhanced. Furthermore, we utilized MAPbBr3/p-g-C3N4 NCs as a photocatalyst to carry out the photocatalytic reduction of pnitrophenol (PNP) under visible-light irradiation. A significant photoreduction rate (kPNP) of PNP was observed in the photocatalytic reaction, which indicated the great potential of MAPbBr3/p-g-C3N4 NCs to convert solar energy into chemical energy. In particular, the present investigation opens a new field for organolead bromide perovskites in applications in photocatalysis, as well as related photoelectric conversion.
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著作名稱:An electrochemical method to enhance the performance of metal oxides for photoelectrochemical water oxidation, J. Mater. Chem. A, 2016, 4, 2849-2855. [SCI, IF:7.44]
年度:2016
類別:期刊論文
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著作名稱:Organolead Halide Perovskite Nanocrystals: Branched Capping Ligands Control Crystal Size and Stability, Angew. Chem. Int. Ed. 2016, 128 (31), 9010-9014 [SCI, IF:11.261]
年度:2016
類別:期刊論文
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著作名稱:Graphene quantum dots conjugated with polymers for two-photon properties under two-photon excitation, Nanoscale, 2016, 8, 16874-16880. [SCI, IF:7.76]
年度:2016
類別:期刊論文
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著作名稱:Two-Photon Photoexcited Photodynamic Therapy and Contrast Agent with Antimicrobial Graphene Quantum Dots, ACS Appl. Mater. Interfaces, 2016,8, 30467-30474. [SCI, IF:7.145]
年度:2016
類別:期刊論文
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著作名稱:Towards Understanding Unusual Photoluminescence Intensity Variation of Ultrasmall Colloidal PbS Quantum Dots with the Formation of Thin CdS Shell, Phys. Chem. Chem. Phys. 2016, 18 (46), 31828-31835. [SCI, IF:4.449]
年度:2016
類別:期刊論文
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著作名稱:Interfacial charge carrier dynamics of cuprous oxide-reduced graphene oxide (Cu2O-rGO) nanoheterostructures and their related visible-light-driven photocatalysis, Appl. Catal. B: Environmental, 2017, 204, 21-32. [SCI, IF: 9.446]
年度:2016
類別:期刊論文
摘要:We demonstrated a facile and green preparation of cuprous oxide-reduced graphene oxide (Cu2O-rGO) nanoheterostructures through a photochemical reaction. The density of Cu2O nanocubes (NCs) grown on the rGO surface can be well controlled by modulating the concentration of GO employed in the reaction. Because of the relatively low potential of Fermi level of rGO, the photoexcited electrons on the conduction band (CB) of Cu2O NCs preferentially transfer to rGO, simultaneously leaving photogenerated holes on the valence band (VB) of Cu2O, resulting in the notable charge carrier separation properties. Time-resolved photoluminescence (TRPL) spectra were collected to quantitatively analyze the electron transfer rate constant (ketket) between Cu2O NCs and rGO, and the dependence of the ket on the rGO constituent in Cu2O-rGO nanoheterostructures. Among all the samples tested, the Cu2O-rGO nanoheterostructure with the rGO constituent of 2 wt.% (denoted as Cu2O-rGO-2) displayed the largest ket as well as the most pronounced charge separation property. The optimized Cu2O-rGO-2 showed the best methyl orange (MO) photocatalytic degradation performance, which was highly consistent with the trend of the obtained ketket results. As compared with relevant commercial products, such as N-doped P-25 TiO2 and commercial Cu2O powders, the Cu2O-rGO-2 exhibited superior efficiency toward MO degradation under visible light illumination, illustrating its potential for applications in relevant photoelectric conversion processes. The recycling trial showed that the Cu2O-rGO-2 has promising potential for use in the long-term course of photocatalysis to degrade organic pollutants. Furthermore, the photocatalytic efficiency evaluated under natural sunlight demonstrated that the present Cu2O-rGO nanoheterostructure could effectively harvest the energy of solar spectrum and converted it into the chemical energy for organic pollutants degradation. The current study could provide great insights into the design of semiconductor/graphene composites which exhibit remarkable charge separation properties for practical applications in the organic pollutants photodegradation, solar fuel generation as well as photovoltaic devices.
關鍵字: Cu2O; Graphene; Charge carrier dynamics; Photocatalysis; Visible-light-driven
著作名稱:Size‐Tunable Synthesis of Hollow Gold Nanospheres through Control of Reaction Temperature. Part. Part. Syst. Charact. 2016, 34, 1600255. [SCI, IF: 4.367]
年度:2016
類別:期刊論文
摘要:Here, it is demonstrated that the size tunable hollow gold nanospheres (HGNs) of ≈24–122 nm in diameter can be facilely achieved by controlling a signal parameter, reaction temperature, in the synthesis. The varied particle sizes of HGNs result in highly tunable surface plasmon resonance (SPR) absorption in the entire visible to near infrared region of the spectrum, with maximum peak position from 565 to 850 nm when the reaction temperature is varied from 80 to 10 °C. The particle size and structural properties are determined using dynamic light scattering, transmission-mode scanning electron microscopy, and high-resolution transmission electron microscopy. The optical properties are characterized using UV–vis spectroscopy. A mechanism behind the temperature-dependent HGN synthesis is explained by the thermodynamics of homogeneous nuclei formation of the cobalt scaffold. Discrete dipole approximation calculations are performed to simulate the SPR spectrum and provide insight into the relation between the SPR absorption and structural details of the HGNs. This study demonstrates a simple yet effective method based on temperature control for synthesizing produce size tunable HGNs with varying properties of interest for different applications.
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著作名稱:Uniform carbon-coated CdS core–shell nanostructures: synthesis, ultrafast charge carrier dynamics, and photoelectrochemical water splitting, J. Mater. Chem. A, 2016, 4, 1078-1086. [SCI, IF:7.44]
年度:2015
類別:期刊論文
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著作名稱:Synthesis, Optical Properties, and Exciton Dynamics of Organolead Bromide Perovskite Nanocrystals, J. Phys. Chem. C 2015, 119, 26672-26682. [SCI, IF:4.77]
年度:2015
類別:期刊論文
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著作名稱:Shell-thickness dependent electron transfer and relaxation in type-II core–shell CdS/TiO2 structures with optimized photoelectrochemical performance, J. Mater. Chem. A, 2015, 45, 22672-22635. [SCI, IF:7.44]
年度:2015
類別:期刊論文
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著作名稱:Ultrafast Exciton Dynamics in InGaN/GaN and Rh/Cr2O3 Nanoparticle Decorated InGaN/GaN Nanowires, J. Phys. Chem. Lett. 2015, 6, 2649-2656. [SCI, IF:7.45]
年度:2015
類別:期刊論文
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著作名稱:Modulation of Charge Carrier Dynamics of NaxH2-xTi3O7-Au-Cu2O Z-Scheme Nanoheterostructures through Size Effect, Appl. Catal. B: Environmental, 2015, 163, 343-351. [SCI, IF:8.328]
年度:2015
類別:期刊論文
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著作名稱:Design of Novel Metal Nanostructures for Broadband Solar Energy Conversion, International Journal of Spectroscopy 2015, 147423. [SCI]
年度:2014
類別:期刊論文
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著作名稱:Mechanisms behind Plasmonic Enhancement of Photocurrent in Metal Oxides, Austin J Nanomed Nanotechnol. 2014, 2, 4.[SCI]
年度:2014
類別:期刊論文
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著作名稱:Surface Passivation of TiO2 Nanowires Using a Facile Precursor-Treatment Approach for Photoelectrochemical Water Oxidation, J. Phys. Chem. C, 2014, 118, 15086-15094. [SCI, IF:4.77]
年度:2014
類別:期刊論文
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著作名稱:Multicolored Cd1-xZnxSe quantum dots with type-I core/shell structure: single-step synthesis and their use as light emitting diodes, 2014, 6, 3881-3888. [SCI, IF:7.39]
年度:2014
類別:期刊論文
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著作名稱:A Facile Green Antisolvent Approach to Cu2+-doped ZnO Nanocrystals with Visible-Light-Responsive Photoactivities, Nanoscale 2014, 6, 8796-8803.[SCI, IF:7.76]
年度:2014
類別:期刊論文
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著作名稱:Studies on the Photocatalysis of Core-Shelled SiO2-Ag Nanospheres by Controlled Surface Plasmon Resonance under Visible Light, Appl. Surf. Sci. 2014, 311, 399-404.[SCI, IF:2.71]
年度:2014
類別:期刊論文
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著作名稱:Studies on the annealing and antibacterial properties of the silver embedded aluminum/silica nanospheres, Nanoscale Res. Lett. 2014, 9:307. [SCI, IF:2.77]
年度:2014
類別:期刊論文
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著作名稱:Au Nanostructure-Decorated TiO2 Nanowires Exhibiting Photoactivity Across Entire UV-Visible Region for Photoelectrochemical Solar Water Splitting, Nano Letters 2013, 13, 3817-3823. [SCI, IF:13.59]
年度:2013
類別:期刊論文
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著作名稱:Au/ZnS core/shell nanocrystals as an efficient anode photocatalyst in direct methanol fuel cells, Chem. Commun., 2013, 49, 8486-8488. [SCI, IF:6.83]
年度:2013
類別:期刊論文
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著作名稱:Optical Properties and Exciton Dynamics of Alloyed Core/Shell/Shell Cd1−xZnxSe/ZnSe/ZnS Quantum Dots, ACS Appl. Mater. Interfaces, 2013, 5, 2893-2900. [SCI, IF:7.145]
年度:2013
類別:期刊論文
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著作名稱:Ag-Nanoparticle-Decorated SiO2 Nanospheres Exhibiting Remarkable Plasmon-Mediated Photocatalytic Properties, J. Phys. Chem. C, 2012, 116 (35), 19039–19045. [SCI, IF:4.77]
年度:2012
類別:期刊論文
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著作名稱:Interfacial Charge Carrier Dynamics of the Three-Component In2O3–TiO2–Pt Heterojunction System, J. Phys. Chem. C, 2012, 116 (4), 2967–2975. [SCI, IF:4.77]
年度:2012
類別:期刊論文
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著作名稱:Au-decorated NaxH2−xTi3O7 nanobelts exhibiting remarkable photocatalytic properties under visible-light illumination, Appl. Catal. B: Environmental 2010, 97, 389–397. [SCI, IF:8.328]
年度:2010
類別:期刊論文
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著作名稱:Surface Modification of TiO2 Nanowires for Photoelectrochemical Water Splitting
年度:2017
類別:研討會
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著作名稱:Synthesis and charge carrier dynamics of organolead bromide perovskite/graphitic carbon nitride nanoheterostructures for photocatalytic CO2 reduction
年度:2017
類別:研討會
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著作名稱:還原態氧化石墨烯/氧化亞銅複合結構之載子動力學
年度:2016
類別:研討會
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著作名稱:ULTRAFAST EXCITON DYNAMICS IN ORGANOLEAD BROMIDE PEROVSKITE NANOCRYSTALS
年度:2016
類別:研討會
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著作名稱:Ultrafast interfacial charge transfer dynamics in CdSe quantum dot-sensitized TiO2 for photoelectrochemical solar hydrogen generation
年度:2015
類別:研討會
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著作名稱:Plasmonic enhancement of solar water splitting in Au-decorated TiO2 nanowire array
年度:2013
類別:研討會
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著作名稱:Ternary Quantum Dots with Tunable Emission Wavelength and Their Use as Light Emitting Diodes
年度:2011
類別:研討會
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著作名稱:Cuprous Oxide-Reduced Graphene Oxide Nanoheterostructures for Visible-Light-Driven Photocatalysis
年度:2016
類別:研討會
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