| 著作名稱： | Green Energy Materials Handbook |
| 年度： | 2019 |
| 類別： |
學術專書
|
| 摘要： | This chapter discusses the experimental investigations of employing the in-situ X-ray and neutron diffraction technique to study the structural disorder and phase transition of different anode and cathode materials in lithium-ion batteries (LIBs) and Na-ion batteries. It explains about employing in-situ X-ray and the in-operando high-resolution neutron-scattering studies on analyzing the structural distortions and phase transition that occurred on commercial-type LIB and Na-ion batteries during the charging/discharging conditions. Rechargeable LIBs have attracted much attention on energy storage due to their high energy density and long cycle life for increasing demand of portable electric devices, electric vehicles, hybrid electric vehicles, plug-in hybrid electric vehicles, and grid energy storage system. The 2032 coin-type cells consisting of a test electrode, lithium foil as a counter electrode, and a microporous separator were assembled in an Ar-filled glovebox. Lithium transferability in graphite is the rate-limiting factor for the charge capability at low temperatures. |
| 關鍵字： | |
| 著作名稱： | Ten-Chin Wen and Chia-Chin Chang, “Effect of Additives in the Preparation of PbO2 Deposits on the Electrocatalytic Activity”, Surface Modification Technologies V, Edited by T. S. Sudarshan and J. F. Braza, the Institute of Materials p.611-617(1992). (Book) |
| 年度： | 1992 |
| 類別： |
學術專書
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Solid electrolyte interphase layer formation on mesophase graphite electrodes with different electrolytes studied by small‐angle neutron scattering |
| 年度： | 2021 |
| 類別： |
期刊論文
Journal of the Chinese Chemical Society
|
| 摘要： | electrolyte additives, graphite anode, lithium-ion battery, neutron scattering, solid electrolyteinterphase |
| 關鍵字： | electrolyte additives, graphite anode, lithium-ion battery, neutron scattering, solid electrolyteinterphase |
| 著作名稱： | Impact of Silicon Content within Silicon-Graphite Anodes on Performance and Li Concentration Profiles of Li-Ion Cells using Neutron Depth Profiling |
| 年度： | 2021 |
| 類別： |
期刊論文
Journal of The Electrochemical Society
|
| 摘要： | Due to its high specific capacity, silicon is a promising candidate to substitute conventional graphite as anode material in lithium-ion batteries. However, pure silicon-based anodes suffer from poor capacity retention, mainly due to a large volume change during cycling, which results in material pulverization and other side reactions. Therefore, alternative compositions with lowered silicon content and a similar working voltage as graphite are favored, e.g. silicon-graphite (SiG), as they can reduce these volume change and side reactions while maintaining a high capacity. Here, neutron depth profiling (NDP) offers the unique possibility to quantify non-destructively the lithium concentration profile over the depth of these electrodes. In this study, the (de-)intercalation phenomena during (de-)lithiation in SiG porous anodes with silicon contents ranging from 0 wt% to 20 wt% is investigated for the first time using ex situ NDP during the initial discharge at defined depths of discharge (DODs) states. These findings are complemented by a conventional electrochemical analysis of the first full cycle with a charge/discharge rate of C/20. While the specific capacity is observed to increase with higher silicon content, NDP directly reveals a homogeneous irreversible lithium accumulation within the entire electrode depth. |
| 關鍵字： | |
| 著作名稱： | Preferential Lattice Expansion of Polypropylene in a Trilayer Polypropylene/Polyethylene/Polypropylene Microporous Separator in Li-ion Batteries |
| 年度： | 2021 |
| 類別： |
期刊論文
Scientific Reports
|
| 摘要： | The abnormal lattice expansion of commercial polypropylene (PP)/polyethylene (PE)/polypropylene(PP) separator in lithium-ion battery under different charging current densities was observed by in-situ X-ray diffraction. Significant lattice changes of both PP and PE were found during the low current density charging. The capacity fading and the resistance value of the cell measured at 0.025 C (5th retention, 92%) is unexpectedly larger than that at 1.0 C (5th retention, 97.3%) from the electrochemical impedance spectroscopic data. High-resolution scanning electron microscopy
is employed to witness the pore changes of the trilayered membrane. Density functional theory calculations were used to investigate the mechanism responsible for the irregular results. The calculations revealed that the insertion of Li-ion and EC molecule into PP or PE are thermodynamically favourable process which might explain the anomalous significant lattice expansion during the low current density charging. Therefore, designing a new separator material with a more compact crystalline structure or surface modification to reduce the Li insertion during the battery operation is
desirable. |
| 關鍵字： | |
| 著作名稱： | Petroleum waste hydrocarbon resin as a carbon source modified on a Si composite as a superior anode material in lithium ion batteries |
| 年度： | 2021 |
| 類別： |
期刊論文
Materials Chemistry and Physics
|
| 摘要： | We demonstrate impressive electrochemical performance of a silicon(Si)/carbon(C) composite prepared by mixing an appropriate concentration of hydrocarbon resin, Si powder, and polyacrylic acid followed by a simple ball milling process and heat treatment at temperatures ranging from 600◦C to 900 ◦C. The Si/C composite annealed at 700 ◦C achieved a significantly high discharge capacity (2291 mAh g |
| 關鍵字： | Si/C composite Anode material Lithium ion battery Planetary ball-milling/heat treatment |
| 著作名稱： | Cu3Si enhanced crystallinity and dopamine derived nitrogen doping into carbon coated micron-sized Si/Cu3Si as anode material in lithium-ion batteries |
| 年度： | 2021 |
| 類別： |
期刊論文
Electrochimica Acta
|
| 摘要： | A chemical vapor decomposition (CVD) enhanced carbon coated Si/Cu3Si composite aggregate (C-Si/Cu3Si@C) is prepared as anode material to alleviate volume expansion and improve the electrochemical performance for lithium-ion batteries (LIBs). In this work, micron-sized C-Si/Cu3Si@C is fabricated through self-assembling of dopamine as first carbon precursor on irregularly shaped and sub-micron-sized Si/Cu3Si composite, followed by CVD with ethylene (C2H4) as second carbon precursor. Besides, dopamine not only self-assembles on the surface of Si/Cu3Si composite but also grows into sheet-like film that supports and connects Si/Cu3Si composite into micron-sized aggregate. In addition to CVD, Cu3Si induces catalytic chemical vapor deposition (CCVD), which enhances integrality of the carbon shell as well as reinforce nitrogen doping into carbon shell to enhance conductivity. Therefore, the C-Si/Cu3Si@C composite performs in optimum condition when the cycle is stable, attaining delithiation capacity of 2101 mAh g−1, coulombic efficiency of 84.7% for the 1st cycle and achieves capacity retention of 82.9% after 100 cycles. |
| 關鍵字： | Lithium-ion batteriesAnodeSi/Cu3SiDopamineChemical vapor decomposition |
| 著作名稱： | Room temperature synthesis of SiOx/rGO composite as anode material in lithium ion battery |
| 年度： | 2021 |
| 類別： |
期刊論文
Materials Letters
|
| 摘要： | We explore a simple, room temperature, bottom up approach for the synthesis of SiOx dispersed over rGO(reduced graphene oxide) sheets forming SiOx/rGO composite. X-ray diffraction analysis confirmed the formation of SiOx with the major peak position at 21.9° Bragg angle. The microstructure of the composite revealed a layer like morphology and the uniform distribution of SiOx as observed by the element map-ping in the transmission electron microscopy. The SiOx/rGO composite was used as anode in lithium ion battery and the composite achieved appreciable capacity (749 mAh g-1 @100 mA g-1) in the first cycle and 61 mAh g-1 at 100 charge/discharge cycles with 99% coulombic efficiency. |
| 關鍵字： | Composite materials, Energy storage and conversion, Microstructure, Room temperature synthesis, Bottom up approach |
| 著作名稱： | An electrolyte additive with boron-nitrogen-oxygen alkyl group enabled stable cycling for high voltage LiNi0.5Mn1.5O4 cathode in lithium-ion battery |
| 年度： | 2020 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Enhanced capacity and significant rate capability of Mn3O4/reduced graphene oxide nanocomposite as high performance anode material in lithium-ion batteries |
| 年度： | 2020 |
| 類別： |
期刊論文
Applied Surface Science
|
| 摘要： | We report enhanced capacity, significant rate capability of Mn3O4 microsheet and reduced graphene oxide (Mn3O4/rGO) nanocomposite as high performance anode material in lithium ion battery. The Mn3O4/rGO nanocomposite prepared by a facile, low temperature chemical reduction procedure has achieved superior capacity of ~677 mAh g−1 (current rate 123 mA g−1) after 150 charge/discharge cycles (retention 85%) and appreciable rate capability of 640 mAh g−1 @1.2 A g−1. The comparative investigation reveals the distinguished electrochemical performance of Mn3O4/rGO as compared with MnO2/rGO, MnO2 and graphene oxide. Lithium ion diffusion coefficient of Mn3O4/rGO (2.4 × 10−10 m2 s−1) is higher than MnO2/rGO, MnO2 and graphene oxide that facilitates the smooth passage of Li ions in the composite delivering noticeable electrochemical performance. Mn3O4/rGO is synthesized by the simple chemical reduction of MnO2 nanorod/rGO nanocomposite and the procedure can be extended for the synthesis of other potentially useful, simple/complex metal oxides (varying shape and size) as anode materials in lithium ion batteries. |
| 關鍵字： | Li ion batteriesMn3O4/rGO nanocompositeAnode materialChemical synthesisEnergy storage |
| 著作名稱： | Cyclability Evaluation on Si Based Negative Electrode in Lithium Ion Battery by Graphite Phase Evolution: An Operando X-Ray Diffraction Study |
| 年度： | 2019 |
| 類別： |
期刊論文
Scientific Report
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | X-ray Absorption Spectroscopy and In-Operando Neutron Diffraction Studies on Local Structure Fading Induced Irreversibility in a 18650 Cell with P2–Na2/3Fe1/3Mn2/3O2 Cathode in a Long Cycle Test |
| 年度： | 2018 |
| 類別： |
期刊論文
The Journal of Physical Chemistry C
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | In operando detection of lithium diffusion behaviors at low temperature in 18650 Li-ion battery anode |
| 年度： | 2018 |
| 類別： |
期刊論文
Physica B Condensed Matter
|
| 摘要： | Lithium diffusion process in an 18650 cell was investigated in-operando using neutron diffraction. The graphite anode delithiation rate and the amount of discharge capacity during the discharging process were correlated with the temperature and current rate. At room temperature, the lithium diffusion rate in LiC6 phase at the high rate capability (C/5) is same as at low rate capability (C/20), which means that lithium diffusion in LiC6 crystal phase is independent of the current rate in this range during the discharge process. Lowering temperature to −20 °C decreases both the lithium diffusion and capacity, although the latter can be partially recovered by using lower C-rate. |
| 關鍵字： | Li-ion batteryLow temperatureNeutronSIKA18650 batteryGraphite |
| 著作名稱： | Freestanding Three-Dimensional CuO/NiO Core–Shell Nanowire Arrays as High-Performance Lithium-Ion Battery Anode |
| 年度： | 2018 |
| 類別： |
期刊論文
Scientific Reports
|
| 摘要： | We demonstrate significant improvement of CuO nanowire arrays as anode materials for lithium ion batteries by coating with thin NiO nanosheets conformally. The NiO nanosheets were designed two kinds of morphologies, which are porous and non-porous. By the NiO nanosheets coating, the major active CuO nanowires were protected from direct contact with the electrolyte to improve the surface chemical stability. Simultaneously, through the observation and comparison of TEM results of crystalline non-porous NiO nanosheets, before and after lithiation process, we clearly prove the effect of expected protection of CuO, and clarify the differences of phase transition, crystallinity change, ionic conduction and the mechanisms of the capacity decay further. Subsequently, the electrochemical performances exhibit lithiation and delithiation differences of the porous and non-porous NiO nanosheets, and confirm that the presence of the non-porous NiO coating can still effectively assist the diffusion of Li+ ions into the CuO nanowires, maintaining the advantage of high surface area, and improves the cycle performance of CuO nanowires, leading to enhanced battery capacity. Optimally, the best structure is validated to be non-porous NiO nanosheets, in contrary to the anticipated porous NiO nanosheets. In addition, considering the low cost and facile fabrication process can be realized further for practical applications. |
| 關鍵字： | Batteries Nanowires |
| 著作名稱： | Influence of Glucose Derivatives on Ball Milled Si for Negative Electrodes with High Area Capacity in Lithium-Ion Batteries |
| 年度： | 2018 |
| 類別： |
期刊論文
ACS Sustainable Chemistry & Engineering (ACS Publications)
|
| 摘要： | Robust surface treatments on ball-milled Si are proposed to industrially fabricate negative electrodes with high area capacity in LIBs. |
| 關鍵字： | Glucose modification; High-energy mechanical milling; Lithium-ion batteries; Negative electrode; Si |
| 著作名稱： | Mechanochemical synthesis of Si/ Cu3Si-based composite as negative electrode materials for lithium ion battery |
| 年度： | 2018 |
| 類別： |
期刊論文
Scientific Reports
|
| 摘要： | Mechanochemical synthesis of Si/Cu3Si-based composite as negative electrode materials for lithium ion battery is investigated. Results indicate that CuO is decomposed and alloyed with Si forming amorphous Cu-Si solid solution due to high energy impacting during high energy mechanical milling (HEMM). Upon carbonization at 800 °C, heating energy induces Cu3Si to crystallize in nanocrystalline/amorphous Si-rich matrix enhancing composite rigidity and conductivity. In addition, residual carbon formed on outside surface of composite powder as a buff space further alleviates volume change upon lithiation/delithiation. Thus, coin cell made of C-coated Si/Cu3Si-based composite as negative electrode (active materials loading, 2.3 mg cm-2) conducted at 100 mA g-1 performs the initial charge capacity of 1812 mAh g-1 (4.08 mAh cm-2) columbic efficiency of 83.7% and retained charge capacity of 1470 mAh g-1 (3.31 mAh cm-2) at the end of the 100th cycle, opening a promised window as negative electrode materials for lithium ion batteries. |
| 關鍵字： | |
| 著作名稱： | Nano-sized Tin Oxide-Modified Graphite Composite as Efficient Anode Material for Lithium Ion Batteries |
| 年度： | 2018 |
| 類別： |
期刊論文
International Journal of Electrochemistry Science
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | The mechanism of the sodiation and desodiation in Super P carbon electrode for sodium-ion battery |
| 年度： | 2017 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | The sodiation and desodiation of sodium (Na) into the Super-P carbon anode material were investigated using electrochemical analyses, high-resolution transmission electron microscopy (HRTEM), and neutron powder diffraction (NPD). In the sodiated Super-P carbon, sodium is stored both in the graphite interlayer space of carbon nano-particles and pores between the particles. Sodium metal clusters found in micro-pores between the carbon particles are responsible for the large irreversible capacity of the Super-P electrode. The graphite interlayer distance increases on sodiation from 3.57 Å to two distinct values of ∼3.84 and 4.41 Å. The mechanism of the process is discussed. |
| 關鍵字： | Sodium-ion battery, Anode, Super P, carbon, Neutron powder diffraction |
| 著作名稱： | Synthesis of MnOx/reduced graphene oxide nanocomposite as an anode electrode for lithium-ion batteries |
| 年度： | 2017 |
| 類別： |
期刊論文
Ceramics International
|
| 摘要： | We report the high performance of the manganese oxide/reduced graphene oxide (MnOx/rGO) nanocomposite as an anode electrode of a lithium-ion battery. The composite is synthesized by a low temperature (83 °C) chemical solution reaction, and shows relatively high specific capacities (660 mAh g−1) after 50 cycles. For MnOx/rGO composites, the cycling stability is increased remarkably as compared to that seen with individual MnOx, and this is due to the synergistic effects of both the components in the composite. The rGO acts as a conductive buffer layer that suppresses the volume change of MnOx, and simultaneously promotes the conductivity of MnOx. The functional groups of graphene oxide facilitate MnOx formation at low temperature, and this retains the MnOx-graphene oxide connection, thus improving the capacity and cycling stability. |
| 關鍵字： | MnO2; Reduced graphene oxide; Anode materials; Li-ion batteries |
| 著作名稱： | The synergistic effects of combining the high energy mechanical milling and wet milling on Si negative electrode materials for lithium ion battery |
| 年度： | 2017 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | The submicro-sized and nanostructured Si aggregated powder is prepared by combinational routes of high energy mechanical milling (HEMM) and wet milling. Milled Si powder is investigated by particle size analyzer, SEM, TEM, XPS and XRD as well as the control ones. Its electrode is also investigated by in situ XRD and electrochemical performance. Morphology reveals that combining the high energy mechanical milling and wet milling not only fracture primary Si particles but also form submicro-sized Si aggregates constructed by amorphous and nanocrystalline phases. Moreover, XPS shows that wet milling in ethanol trigger Sisingle bondOsingle bondCH2CH3 bonding on Si surface might enhance the SEI formation. In situ XRD analysis shows negative electrode made of submicro-sized Si aggregated powder can effectively suppress formation of crystalline Li15Si4 during lithiation and delithiation due to amorphous and nanocrystalline construction. Thus, the submicro-sized Si powder with synergistic effects combining the high energy mechanical milling and wet milling in ethanol as negative electrode performs better capacity retention. |
| 關鍵字： | Lithium-ion battery, Anode, Si, High energy mechanical milling, Wet milling |
| 著作名稱： | Facile, low temperature synthesis of SnO2/reduced graphene oxide nanocomposite as anode material for lithium-ion batteries |
| 年度： | 2017 |
| 類別： |
期刊論文
Applied Surface Science
|
| 摘要： | We demonstrate a facile, single step, low temperature and energy efficient strategy for the synthesis of SnO2-reduced graphene oxide (RGO) nanocomposite where the crystallization of SnO2 nanoparticles and the reduction of graphene oxide takes place simultaneously by an in situ chemical reduction process. The electrochemical property of the SnO2-RGO composite prepared by using low concentrations of reducing agent shows better Li storage performance, good rate capability (378 mAh g−1 at 3200 mA g−1) and stable capacitance (522 mAh g−1 after 50 cycles). Increasing the reductant concentration lead to crystallization of high concentration of SnO2 nanoparticle aggregation and degrade the Li ion storage property. |
| 關鍵字： | SnO2, Nanocomposite, Lithium-ion battery, Reduced graphene oxide |
| 著作名稱： | Mixture of Ionic Liquid and Organic Carbonate as an Electrolyte for LiFePO4 Battery |
| 年度： | 2016 |
| 類別： |
期刊論文
International Journal of Electrochemical Science
|
| 摘要： | In the interest of expanding the available options for safe and inexpensive electrolyte in lithium ion batteries, we examined a novel electrolyte consisting of 30% IL (triethylmethylammonium bis(trifluoromethylsulfonyl)imide, N1222-TFSI) mixed with 70% commercial carbonate electrolyte (EC/DMC 1:1 by wt%, 0.78 mol kg-1 LiPF6) to form a hybrid electrolyte. The hybrid electrolyte failed to ignite after exposure to flame, a demonstration of high thermal stability. The aluminum corrosion is inhibited in N1222-TFSI mixed carbonate electrolyte, while the N-methyl-N-propylpyrrolidinium TFSI mixed carbonate electrolyte experienced serious pitting corrosion. The electrolyte has been observed with the LiFePO4 as positive electrode and the mesophase graphite as negative electrode in 18650 full cells. The electrochemical properties of hybrid electrolyte for the LiFePO4 electrode at 25oC and 60oC showed improved performance at high temperature in comparison to commercial electrolyte EC/DMC (1:1 by wt%) 0.78 mol kg-1 LiPF6. Vinylene carbonate (VC) as electrolyte additive in hybrid electrolyte at 2% addition was found to enhance the cycling performance at 25oC and 60oC, however a decrease in cell performance was observed at -10oC. |
| 關鍵字： | lithium-ion batteries, vinylene carbonate, ionic liquid, triethylmethylammonium bis(trifluoromethylsulfonyl) amide |
| 著作名稱： | Lithiation-induced crystal restructuring of hydrothermally prepared Sn/TiO2 nanocrystallite with substantially enhanced capacity and cycling performance for lithium-ion battery |
| 年度： | 2016 |
| 類別： |
期刊論文
RSC Advances
|
| 摘要： | A Sn-doped TiO2 nanocrystallite with the composition of Sn0.1Ti0.9O2 was prepared by hydrothermal co-precipitation followed by thermal annealing at 600 °C for 2 hours. Results combining high-resolution transmission electron microscopy, in situ XRD, ex situ XAS, and electrochemical impedance spectroscopy indicate that Sn0.1Ti0.9O2 underwent restructuring to give Sn-substituted TiO2 (Sn to Ti sites) by a lithiation reaction at 0.1C in a lithium-ion battery. The capacity and cyclability of Sn0.1Ti0.9O2 were increased by ∼73% (to ∼598 mA h g−1) and ∼17.4% compared with those of TiO2 (∼345 mA h g−1 and ∼22%) at 0.1C until the 250th cycle. Our results proved that these improvements were caused by the self-aligned formation of Sn–Ti oxide and the subsequent formation of a SnLix local alloy at Ti sites. |
| 關鍵字： | |
| 著作名稱： | Real-time investigation on the influences of vanadium additives to the structural and chemical state evolutions of LiFePO4 for enhancing the electrochemical performance of lithium-ion battery |
| 年度： | 2014 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | The influences of adding vanadium to the structure evolution and electrochemical performance of LiFePO4 are systematically investigated by in-situ X-ray powder diffraction and X-ray absorption near edge structure spectroscopy. The results indicate that the addition of a small amount of vanadium (less than at 1%) significantly reduces the formation of non-crystalline (highly disordered) triphylite and remnant heterosite phases in the cathode of battery especially at the rate capability higher than 0.5C. The cycle stability of LiFePO4 cathode with vanadium additive after 80 cycles is improved by 14.9% compared to that without vanadium additive. Such an enhancement could be attributed to the ion diffusion kinetics being improved and inactive triphylite being reduced by the supervalent-vanadium additive in cathode during electrochemical redox cycles. |
| 關鍵字： | Lithium iron phosphateX-ray powder diffractionX-ray absorption near edge structureVanadiumLithium ion battery |
| 著作名稱： | Sputtered copper coating on silicon/graphite composite anodefor lithium ion batteries |
| 年度： | 2014 |
| 類別： |
期刊論文
Journal of Alloys and Compounds
|
| 摘要： | A sputtered copper coating on a silicon/graphite composite is investigated as an anode material for lithium
ion batteries (LIBs). Characterization of the material has been performed by X-ray diffraction (XRD),
scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and transmission electron
microscopy (TEM). Results show that the thickness of the copper on the nano-Si/graphite composite
anode is controlled by the duration of copper sputtering. A sputtered copper coating of approximately
12 nm thickness improves the rate capacity, maximum energy density and the elevated temperature
cycling performance of LIBs with silicon/graphite anodes. The presented results confirm that the modification
provided by sputtered Cu to the morphology of the solid/electrolyte interface of the anode surface
is of interest to the next generation of high performance LIBs. |
| 關鍵字： | Lithium ion battery, Silicon based anode, Sputtering |
| 著作名稱： | Maleic-anhydride-grafted ketjen black as the alternative carbon additive for LiFePO4 cathode |
| 年度： | 2013 |
| 類別： |
期刊論文
Electrochimica Acta
|
| 摘要： | tKetjen black (KB) has a large specific surface area and is potentially more effective as the cathode conduc-tive additive. However, large KB flakes often overlay together to form thick stacks. In order to overcomethis problem, maleic anhydride (MA) was grafted onto the KB surface by a plasma-induced method. Sucha MA-KB additive was found to have a more homogeneous distribution in the LiFePO4cathode, whichresulted in a reduction in the electrical resistivity and electrode polarization. As the consequence, greatlyimproved cell performance was achieved, including higher capacity, higher discharge voltage, higher ratecapability, longer cycle lifetime, and a much flatter discharge curve. Detailed analysis on the dischargecurves and the electrochemical impedance spectroscopy showed that although both the electrical resis-tivity and electrode polarization were reduced by the better distribution of the MA-KB additive, thereduction in electrode polarization was more important in cutting the capacity loss. |
| 關鍵字： | Lithium-iron phosphate, Li-ion battery, Ketjen black, Maleic anhydridea |
| 著作名稱： | Rutile-type (Ti,Sn)O2 nanorods as efficient anode materials toward its lithium storage capabilities |
| 年度： | 2013 |
| 類別： |
期刊論文
Nanoscale
|
| 摘要： | A series of rutile-type (Ti,Sn)O2 solid solutions with nanorod architecture were successfully synthesized in this study by varying their calcination temperatures of tin-modified titanium dioxide (Sn/TiO2) nanocomposites under a nitrogen atmosphere. During the delithiation process, the (Ti,Sn)O2 nanorods obtained at 500 C delivered a specific capacity of about 300 mA h g1 and showed minimal
capacity fading even at a high current density of 3 A g1. |
| 關鍵字： | |
| 著作名稱： | Effects of Styrene-Butadiene Rubber/Carboxymethylcellulose (SBR/CMC) and Polyvinylidene Difluoride (PVDF) Binders on Low Temperature Lithium Ion Batteries |
| 年度： | 2013 |
| 類別： |
期刊論文
Journal of The Electrochemical Society
|
| 摘要： | Effects of styrene-butadiene rubber/carboxymethylcellulose (SBR/CMC) and polyvinylidene difluoride (PVDF) binders
on the electrochemical characteristics of a type of microsize MCMB (mesocarbon microbeads) anode (SMA) at low temperature are investigated by cold/heat shock testing, differential scanning calorimetry, scanning electron microscopy, electrochemical impedance spectroscopy, coin cell testing and 18650 full cell testing. Under low temperature conditions and compared to the SMA
electrode with a SBR/CMC binder, the SMA electrode with a PVDF binder has lower impedance, lower charge transfer resistance, better rate capability and superior cycleability. |
| 關鍵字： | |
| 著作名稱： | (Sn-Ti)O2 nanocomposites for high-capacity and high-rate lithium-ion storage |
| 年度： | 2013 |
| 類別： |
期刊論文
Electrochimica Acta
|
| 摘要： | (Sn-Ti)O2 solid solution nanoparticles (denoted (Sn-Ti)O2-500) are prepared by application of one step of chemical treatment followed by calcination in N2 at 500°C for 2h. Transmission electron microscopic (TEM) observations reveal a nanoparticle shape change from needle-like to rod-like after heat treatment. Formation of a (Sn-Ti)O2 solid solution is confirmed by X-ray diffraction (XRD) analysis. The electrochemical properties of the (Sn-Ti)O2 solid solution are studied by cyclic voltammetric and coin cell tests. Electrochemical property results show that (Sn-Ti)O2-500 delivers a specific capacity of about 300mAhg?1, excellent cycle-life performance and high rate-capability during the delithiation process. Inductively coupled plasma results indicate a Sn content in (Sn-Ti)O2-500 of about 10.1% tin to titanium. The promising electrochemical characteristics of (Sn-Ti)O2-500 appear well suited for high-power negative electrodes of lithium ion batteries.[Copyright &y& Elsevier] |
| 關鍵字： | |
| 著作名稱： | Electrochemical method for detecting ATP by 26S proteasome modified gold electrode |
| 年度： | 2013 |
| 類別： |
期刊論文
Sensors and Actuators B: Chemical
|
| 摘要： | Electrochemical detection for adenosine-5’-triphosphate (ATP) is developed using a 26S proteasome modified gold electrode. In this method, the 26S proteasome is self-assembled onto the surface of a gold electrode, forming a 26S-gold electrode probe which can detect ATP. When the 26S-gold electrode reacts with a solution without ATP, the 26S proteasome on the electrode surface separates into 20S proteasome and PA700/19S subcomplexes, the properties of surface charges of 26S-gold electrode inhibiting electrolyte/electrode electron transmission. When ATP is present in the solution, the 26S proteasome selfassembles via ATP binding, the surface of 26S-gold electrode is turned into electroneutrality, and allows electrolyte/electrode electron transmission in proportion to the amount of ATP present. This mechanism is tested for electrochemical detection of ATP, with experimental results showing that the redox currents change with changing ATP concentrations in a linear fashion. ATP concentration can be determined over
a range from 0.5 to 2.0 mM by linear sweep voltammetry. Moreover, the proposed method is successfully applied to the recognition and quantification of ATP in pig plasma. |
| 關鍵字： | ATP, Electrochemical assay, 26S proteasome, Linear sweep voltammetry |
| 著作名稱： | Trimethyl borate and triphenyl borate as electrolyte additives for LiFePO4 cathode with enhanced high temperature performance |
| 年度： | 2012 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | Alkyl- and phenyl-substituted borate anion receptors, triphenyl borate (TPB) and trimethyl borate (TMB), are investigated as electrolyte additives in lithium ion batteries (LiFePO4 cathode, 1 M LiPF6 EC-DMC 1:1 electrolyte) at 25 and 60 °C. TPB shows formation of a thick surface/electrolyte interface (SEI) which hampers ion flow and does not protect the electrode from degradation. Although useful at 25 °C, TPB at 60 °C results in only 7% capacity after 100 cycles, whereas 0.1 M TMB results in 53% capacity. TMB performance improves with increasing concentration. TMB also suppresses thermal decomposition of the electrolyte and formation of the SEI film. |
| 關鍵字： | |
| 著作名稱： | Effects of Chemical Dispersant and Wet Mechanical Milling Methods on ConductiveCarbon Dispersion and Rate Capabilities of LiFePO4 Batteries |
| 年度： | 2012 |
| 類別： |
期刊論文
Journal of the Chiniese Chemical Society
|
| 摘要： | The dispersion state of conductive carbons in the cathodes of lithium ion batteries fabricated with a dispersant and with/without mechanical milling are considered with regard to the batteries’ charge–discharge properties. Suspensions of Ketjen black (KB, EC 300J and EC 600JD) are dispersed in an organic solvent. Ball milling is then performed, modifying the particle sizes and structures. Results show improved dispersion but with collateral reduction of both maximum and average particle sizes. The more fragile EC 600JD, after ballmilling, is broken into more small segments than EC 300J, but with segment density high enough for loose coupling to form networks. Therefore, the electron conduction of EC600JD after ball milling is better than EC 300J. The high-rate discharge capacity of EC600JD after ball milling is also better than that of EC 300J. However, rate capabilities decrease with increasing milling time. |
| 關鍵字： | Conductive carbon; Lithium ion batteries; Dispersion; Mechanical milling; Hollow structure. |
| 著作名稱： | Compatibility of LiFePO4 and LiNi1/3Mn1/3Co1/3O2 Electrode Materials with Quaternary-ammonium Based Ionic Liquid Mixed with Organic Solvent Electrolyte System |
| 年度： | 2012 |
| 類別： |
期刊論文
Journal of the Chiniese Chemical Society
|
| 摘要： | Ionic liquids (ILs) have been proposed as electrolytes for long-lived and safe LIBs, since they are nonflammability and have low volatility. The interactions between of cathodes (as olivine LiFePO4 or layered LiNi1/3Mn1/3Co1/3O2 (NMC)) and ionic liquid mixed with organic solvent electrolyte were investigated by cyclic voltammetry, electrochemical impedance spectroscopy (EIS), coin cell test, and scanning electron microscope (SEM). The mixed electrolyte contains ethylene carbonate (EC), dimethyl carbonate (DMC) and ionic liquid such as bis(trifluoromethanesulfonyl)imide (TFSI) and tetraethylammonium (N2222). The results show that the LiFePO4 cathode in this mixed electrolyte had better cycling performance than the NMC cathode. |
| 關鍵字： | Conductive carbon; Lithium ion batteries; Dispersion; Mechanical milling; Hollow structure |
| 著作名稱： | Effects of Dispersant on the Conductive Carbon for LiFePO4 Cathode |
| 年度： | 2011 |
| 類別： |
期刊論文
Journal of the Electrochemical Society
|
| 摘要： | Carbon-based electrically conductive particles (cECP) are commonly used to reduce interparticle resistance in Li-ion batteries, but cECP tend to flocculate in the dense slurries used to fabricate electrodes. Herein, a novel dispersant limits flocculated cECP particle size and improves cECP dispersion. The increased cECP efficacy allows reduced addition of carbon to the battery, thereby increasing the ratio of active material to conductive material and increasing volumetric energy density. With/without dispersant LiFePO4/ketjenblack cathodes are examined by scanning electron microscopy (SEM), slurry viscosity, electrochemical redox behavior, electrochemical impendence spectroscopy (EIS) and charge/discharge cycling performance. Discharge capacity, durability and resistance are better for the with-dispersant LiFePO4 cathode. EIS shows reduced interfacial impedance and increased cycling performance for the with-dispersant electrode. SEM shows smooth distribution of nano-scale particles of consistent size with dispersant use. Without dispersant, the cECP particles are micro-scale, with high variability in size and location. It is seen that a good cECP dispersant in the initial electrode slurry improves Li-ion battery performance, primarily because of a more cohesive cECP network between the active material particles. |
| 關鍵字： | Lithium-ion battery, Dispersant, LiFePO4, Conductive additive. |
| 著作名稱： | Vinylene carbonate and vinylene trithiocarbonate as electrolyte additives forlithium ion battery |
| 年度： | 2011 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | Vinylene carbonate (VC) and vinylene trithiocarbonate (VTC) are studied as electrolyte additives in
two kinds of electrolytes: (1) propylene carbonate (PC) and diethyl carbonate (DEC) (1:2 by weight)
1 mol dm?3 LiPF6; (2) ethylene carbonate (EC) and DEC (1:2 by weight) 1 mol dm?3 LiPF6. Characterization
is performed by cyclic voltammetry, impedance spectroscopy, scanning electron microscopy (SEM),
electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectroscopy (XPS) and half cell tests.
Cyclic life is better in either electrolyte with VC than either electrolyte with/without VTC. SEM shows VC
and VTC both form well developed passivation films on the graphite anode, but the films with VTC are
thicker than with VC. EIS shows the VTC films have significantly higher charge transfer resistance. The
VTC film in PC fails to protect against exfoliation. XPS indicates VTC has different reaction pathways in PC
relative to EC. In EC/DEC, VTC forms polymeric C–O–C-like components and sulfide species (C–S–S–C, S
and C–S–C). In PC/DEC, VTC does not form polymeric species, instead forming a film mainly containing LiF
and Li2S. It appears that a thinner polymeric film is preferential. The specific data herein are of interest,
and the general conclusions may help development of improved additives for enhanced Li-ion battery
performance. |
| 關鍵字： | Vinylene carbonate (VC); Vinylene trithiocarbonate (VTC); Electrolyte additive; Lithium ion battery |
| 著作名稱： | The electrochemical method for detecting 26S proteasome |
| 年度： | 2011 |
| 類別： |
期刊論文
Sensors and Actuators B: Chemical
|
| 摘要： | Alkyl- and phenyl-substituted borate anion receptors, triphenyl borate (TPB) and trimethyl borate (TMB),
are investigated as electrolyte additives in lithium ion batteries (LiFePO4 cathode, 1 M LiPF6 EC-DMC 1:1
electrolyte) at 25 and 60 C. TPB shows formation of a thick surface/electrolyte interface (SEI) which
hampers ion flow and does not protect the electrode from degradation. Although useful at 25 C, TPB at
60 C results in only 7% capacity after 100 cycles, whereas 0.1 M TMB results in 53% capacity. TMB
performance improves with increasing concentration. TMB also suppresses thermal decomposition of
the electrolyte and formation of the SEI film. |
| 關鍵字： | 26S proteasome; 1,6-hexanedithiol; Cyclic voltammetry; Electrochemical Impedance spectroscopy. |
| 著作名稱： | Influence of Calcination Temperature of IrO2/Ti Electrodes on Oxygen Reduction |
| 年度： | 2009 |
| 類別： |
期刊論文
Materials Chemistry and Physics
|
| 摘要： | IrO2-coated titanium plate electrocatalysts prepared by a dip-coating method (IrO2/Ti) with different
calcination temperatures are characterized by scanning electron microscope, X-ray diffraction and Xray
photoelectron spectroscopy. The electrocatalytic behavior of the oxygen reduction reaction (ORR) is
evaluated by cyclic voltammetry and galvanostatic electrolysis in 1 moldm−3 KOH solution. The effects
of calcination temperature on the oxygen reduction pathway are examined. Galvanostatic electrolysis
results showthat the reaction pathway on the IrO2/Ti electrode prepared at high calcination temperature
is mainly a two-electron pathway producing H2O2. It is observed that higher calcination temperatures
produce: a more uniform fault-free surface; reduced levels of Cl contamination (residual Cl presumably
from incomplete IrCl3 decomposition during the coating process); higher levels of rutile character of the
IrO2 layer; lower hydration levels. It is confirmed that ORR electrocatalytic behavior on highly hydrated
IrO2 is better than on slightly hydrated IrO2. |
| 關鍵字： | Heat treatment, Oxygen reduction reaction, Oxides, Adsorption, X-ray photo-emission spectroscopy |
| 著作名稱： | Tris(pentafluorophenyl) borane as an electrolyte additive for LiFePO4 battery |
| 年度： | 2009 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | The effects of tris(pentafluorophenyl) borane (TPFPB) additive in electrolyte at the LiFePO4 cathode on the
high temperature capacity fading were investigated by electrochemical impedance spectroscopy (EIS),
cyclic voltammetry (CV), cyclability, SEM and Fourier transform infrared (FTIR). According to the study
results, tris(pentafluorophenyl) borane has the ability to improve the cycle performance of LiFePO4 at high
temperature. LiFePO4 electrodes cycled in the electrolyte without the TPFPB additive show a significant
increase in charge transfer resistance by EIS analysis. SEM and FTIR disclose evidence of surface morphology
change and solid electrolyte interface (SEI) formation. FTIR investigation shows various functional
groups are found on the cathode material surface after high temperature cycling tests. The results showed
an obvious improvement of high temperature cycle performance for LiFePO4 cathode material due to the
TPFPB additive. The observed improved cycling performance and improved lithium ion transport are
attributed to decreased LiF content in the SEI film. |
| 關鍵字： | Lithium-ion battery, Tris(pentafluorophenyl) borane, Electrolyte additive, LiFePO4 |
| 著作名稱： | Tris(pentafluorophenyl) borane as an electrolyte additive to improve the high temperature cycling performance of LiFePO4 cathode |
| 年度： | 2009 |
| 類別： |
期刊論文
Journal of The Electrochemical Society
|
| 摘要： | The capacity fading of LiFePO4 batteries using 1.2 mol dm−3 LiPF6 ethylene carbonate/dimethyl carbonate electrolyte with trispentafluorophenylborane TPFPB additive at 60°C is investigated by cyclic voltammetry, cyclability, electrochemical impedance spectroscopy EIS, and scanning electron microscopy SEM. The cyclability results show that the LiFePO4–Li cell with the TPFPB additive electrolytes exhibits high discharge capacity and good cycling performance at 60°C. The LiFePO4 electrode cycled at 60°C without the TPFPB additive shows a significant increase in charge-transfer resistance by EIS analysis. The TPFPB additive in the electrolyte reduces the difference in the charge-transfer resistance before and after 100 cycles at elevated temperatures. SEM results show that after 100 cycles at 60°C in an electrolyte without TPFPB additive, the LiFePO4 electrode forms a visible material on the electrode surface. The observed material is presumably related with capacity fading in the LiFePO4–Li cell.
The results indicate that TPFPB in the electrolyte prevents the formation of the observed material on the electrode, reduces charge-transfer resistance, and enhances cycling performance of the LiFePO4–Li cells at 60°C. |
| 關鍵字： | |
| 著作名稱： | Evaluation of a photovoltaic energy mechatronics system with a built-in quadratic maximum power point tracking algorithm |
| 年度： | 2009 |
| 類別： |
期刊論文
Solar Energy
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Poly(3-methylthiophene) as a Conductive Additive on LiCoO2 Composite Cathode in Lithium-Ion Battery |
| 年度： | 2008 |
| 類別： |
期刊論文
Journal of New Materials for Electrochemical Systems
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Li-Chia Chen, Chia-Chin Chang, Hsien-Chang Chang, “Electrochemical Oxidation of Histidine at an Anodic Oxidized Boron-Doped Diamond Electrode in Neutral Solution”, Electrochimica Acta, 53 (2008) 2883–2889. |
| 年度： | 2008 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, “Sb-coated Mesophase Graphite Powder as Anode Material for Lithium-Ion Batteries”, Journal of Power Sources, 175 (2008) 874-880. |
| 年度： | 2008 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chi-Chang Lin, Li-Chia Chen, Chien-Hao Huang, Shinn-Jyh Ding, Chia-Chin Chang,Hsien-Chang Chang, "Development of the multi-functionalized gold nanoparticles with Electrochemical-based immunoassay for protein A detection" Journal of Electroanalytical Chemistry 619–620 (2008) 39–45. |
| 年度： | 2008 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chien-Hsin Yang,Feng-Jiin Liu, Liang-Ren Huang, Tzong-Liu Wang, Wen-Churng Lin, Mitsunobu Sato, Cheng-Ho Chen, Chia-Chin Chang, "The application of triphenylamine-based hole-transporting materials in electrochromic devices" Journal of Electroanalytical Chemistry 617 (2008) 101–110. |
| 年度： | 2008 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | The methanol adsorption behavior on platinum/ poly(2,5-dimethoxyaniline) composites for application in methanol sensing |
| 年度： | 2008 |
| 類別： |
期刊論文
Journal of Power Sources
|
| 摘要： | The behavior of methanol adsorption on platinum/poly(2,5-dimethoxyaniline) (Pt/PDMA) composite is investigated using UV–vis spectroscopy (UV–vis) and open circuit potential (OCP). The results of scanning electron microscopy and energy dispersive spectroscopy are used to verify the uniform dispersion of Pt in PDMA. The Fourier transform infrared spectra and OCP results revealed that Pt particles interact with PDMA through the electron-rich nitrogen sites, influencing the oxidation state of PDMA. A model is proposed for themethanol adsorption on Pt particles which changes the interaction between Pt andPDMA. With the proposed model,methanol concentration can be discerned using potentiometric measurements. The results of this study can be applied to methanol sensors for direct methanol fuel cells. |
| 關鍵字： | Direct methanol fuel cells, Methanol adsorption, Methanol sensing, Platinum/poly(2,5-dimethoxyaniline) composites |
| 著作名稱： | Chia-Chin Chang, Li-Jane Her, Ti-Kang Chen, Li-Chia Chen, Jin-Long Hong, "The influence of different electrode fabrication methods and poly(vinylidene fluoride) binders on the anode electrode dimension stability and cyclability in lithium-ion batteries", Journal of New Materials for Electrochemical Systems, 11 (2008) 43-47. |
| 年度： | 2008 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Poly(3-methylthiophene) as a Conductive Additive on LiCoO2 Composite Cathode in Lithium-Ion Battery |
| 年度： | 2008 |
| 類別： |
期刊論文
Journal of New Materials for Electrochemical Systems
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, Li-Jane Her, Li-Chia Chen, Yen-Yu Lee, Shyh-Jiun Liu, Hsien-Ju Tien, “2,2-Dimethoxy-Propane as Electrolyte Additive for Lithium Ion Batteries” Journal of Power Sources, 163 (2007)1059. |
| 年度： | 2007 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang *, Shyh-Jiun Liu, Jeng-Jang Wu, Chien-Hsin Yang “Nano-tin oxide/tin particles on the graphite surface as an anode material for lithium-ion batteries”, Journal of Physic Chemistry: C, 111(2007) 16423-16427. |
| 年度： | 2007 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Hsien-Chang Chang, “The electro-oxidation of formaldehyde at boron-doped diamond electrode”, Analytical Letters, 39(2006)2581. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang and Ten-Chin Wen, "Kinetics and Mechanism of Oxygen Reduction at Hydrous Oxide Film-Covered Platinum Electrode in Alkaline Solution", Electrochimica Acta, 52(2006)623-629. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Li-Jane Her, Jin-Long Hong, Chia-Chin Chang, "Preparation and Electrochemical Characterizations of Poly(3,4-dioxyethylenethiophene)/LiCoO2-Ketjenblack Composite Cathode in Lithium-Ion Battery", J. Power Sources, 161(2006)1247. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Hsien-Chang Chang, "Investigation of electro-oxidation of methanol and benzyl alcohol at boron-doped diamond electrode: Evidence the mechanism for fouling film formation", Journal of Physical Chemistry: B, 110(2006)19426. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang,Li-Chia Chen,Hsien-Chang Chang,Hsien-Ju Tien, "Electrocatalytic Activity of Methanol oxidation at Boron-Doped Diamond Electrode in Alkaline Solution", Journal of the Chinese Chemical Society, 53 (2006)1269. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chien-Hsin Yang,Shyh-Jiun Liu, Chia-Chin Chang, Li-Ying Lin, "Electrochromic devices based on copolymers of 3-Trimethoxysilanylpropyl-N-aniline-2,5-Dimethoxyaniline" Journal of Electroanalytical Chemistry 590 (2006) 161–172. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Hsien-Ju Tien, and Hsien-Chang Chang, “Anodic Oxidation Behaviors of Formaldehyde at Boron-Doped Diamond Electrode”, Journal of the Chinese Chemical Society,53 (2006) 839. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Li-Jane Her, Jin-Long Hong, Chia-Chin Chang, Preparation and Electrochemical Characterizations of Poly(3,4-dioxyethlenethiophene)/LiCoO2 Composite Cathode in Lithium-Ion Battery, J. Power Sources, 157(2006)457. |
| 年度： | 2006 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Shu-Fang Hsu, Shan-Shan Chou, Pau-Yee Lin, Hsien-Chang Chang,Anodic oxidation Behaviors of Methanol and Benzyl Alcohol at Boron-Doped Diamond Electrode, Electrochemistry, 73(2005) 1014. |
| 年度： | 2005 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 三吡啶銅錯合物於玻璃碳電極表面對氧氣還原之電觸媒特性研究 |
| 年度： | 2005 |
| 類別： |
期刊論文
南大學報(數理與科學類)
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, Li-Jane Her, Jin-Long Hong, “Copolymer from Electropolymerization of Thiophene and 3,4-Ethylenedioxythiophene and its Use as Cathode for Lithium Ion Battery”, Electrochim. Acta, 50(2005)4461-4468. |
| 年度： | 2005 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Shyh-Jiun Liu, Cheng-Hsua Huang, and Chia-Chin Chang, “Oxygen Reduction in Phosphate Solution with the Cu(II) Complex of 1,10-phenanthroline at Glassy Carbon Electrode”, Materials Chemistry and Physics, 82(2003)551. |
| 年度： | 2003 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Kinetics of oxygen reduction at RuO2-coated titanium electrode in alkaline solution |
| 年度： | 1997 |
| 類別： |
期刊論文
Journal of Applied Electrochemistry
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Kinetics of oxygen reduction at oxide-derived Pd electrodes in alkaline solution |
| 年度： | 1997 |
| 類別： |
期刊論文
Electrochimica Acta
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang and Ten-Chin Wen, “An Investigation of Thermally Prepared Electrodes for Oxygen Reduction in Alkaline Solution,” Materials Chemistry and Physics, 47(1997) 203. |
| 年度： | 1997 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | A mixture design approach to thermally prepared Ir–Pt–Au ternary electrodes for oxygen reduction in alkaline solution |
| 年度： | 1997 |
| 類別： |
期刊論文
Journal of Applied Electrochemistry
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Kinetics of Oxygen Reduction at IrO2-Coated Titanium Electrodes in Alkaline Solution |
| 年度： | 1996 |
| 類別： |
期刊論文
Journal of the Electrochemical Society
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Yat-June Li, Chia-Chin Chang, and Ten-Chin Wen, “Application of Statistical Experimental Strategies to H2O2 Production on Au/Graphite in Alkaline Solution”, Ind. Eng. Chem. Res., 35(1996)4767. |
| 年度： | 1996 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang and Ten-Chin Wen, “Oxygen Reduction at IrO2-Coated Titanium Electrodes in Alkaline Solution”, Bulletin of Electrochemistry, 11(1995)430. |
| 年度： | 1995 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | The Structural Changes of PbO2 Anodes during Ozone Evolution |
| 年度： | 1993 |
| 類別： |
期刊論文
Journal of the Electrochemical Society
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Ten-Chin Wen and Chia-Chin Chang, “Electrolytic Production of Ozone in Phosphate Solutions Using an Orthogonal-Array Experimentation”, J. CIChE, 23 (1992)387. |
| 年度： | 1992 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Failure Mechanisms of High-Voltage Spinel LiNi0.5Mn1.5O4 with Different Morphologies: Effect of Self-Regulation by Lithium Benzimidazole Salt Additive |
| 年度： | 2023 |
| 類別： |
期刊論文
ACS Sustainable Chemistry and Engineering
|
| 摘要： | High voltage (∼5 V) spinel LiNi0.5Mn1.5O4 (LNMO) has attracted great attention because of its ultrahigh voltage plateau, which can be used as a cathode to reduce pressure in battery management systems. Moreover, compared with layered LiNxMyCzO2 materials, LNMO only requires little amounts of Ni, is cobalt-free for maintaining energy density, is inexpensive, and is lightweight. This study demonstrates two types of primary particles with different morphologies: rectangular and pentahedral. The pentahedron-shaped LNMO has lower surface energy owing to the formation of high valence Ni on the surface, thereby causing gas evolution and a loss in cycle retention, a direct Ni2+/Ni4+ reaction. Conversely, rectangular-shaped LNMO with higher Mn3+ content exhibits a stable electrochemical reaction, which provides a higher surface energy that prevents ethylene carbonate (EC) decomposition on the surface, and thereby, excellent performance is obtained, a parallel reaction of Mn3+/ Mn4+ and Ni2+/ Ni3+. By adding a lithium salt additive, trifluoromethyl benzimidazole (LiTFB), a self-regulation of Ni and Mn ion valences leads to a key reaction on both pentahedral (surface disordering effect) and rectangular (preventing Jahn–Teller distortion effect) LNMO morphologies. The two-electron transfer in the reactions of Ni2+/3+ and Mn3+/4+ of LiTFB-modified LNMOs provides excellent electrochemical performance for further high-energy applications. |
| 關鍵字： | LiMn1.5Ni0.5O4 benzimidazole salt high energy density synchrotron disorder |
| 著作名稱： | Methylboronic acid MIDA ester (ADM) as an effective additive in electrolyte to improve cathode electrolyte interlayer performance of LiNi0.8Co0.15Al0.05O2 electrode |
| 年度： | 2023 |
| 類別： |
期刊論文
SCIENTIFIC REPORTS
|
| 摘要： | We investigated the efectiveness of using methylboronic acid MIDA ester (ADM) as an additive
in an electrolyte to enhance the overall electrochemical and material properties of an LNCAO
(LiNi0.8Co0.15Al0.05O2) cathode. The cyclic stability of the cathode material measured at 40 °C (@ 0.2
C) showed an enhanced capacity of 144.28 mAh g−1 (@ 100 cycles), a capacity retention of 80%, and
a high coulombic efciency (99.5%), in contrast to these same properties without the electrolyte
additive (37.5 mAh g−1, ~ 20%, and 90.4%), thus confrming the efectiveness of the additive. A Fourier
transform infrared spectroscopy (FTIR) analysis distinctly showed that the ADM additive suppressed
the EC-Li+
ion coordination (1197 cm−1 and 728 cm−1) in the electrolyte, thereby improving the
cyclic performance of the LNCAO cathode. The cathode after 100 charge/discharge cycles revealed
that the ADM-containing system exhibited better surface stability of the grains in the LNCAO
cathode, whereas distinct cracks were observed in the system without the ADM in the electrolyte. A
transmission electron microscopy (TEM) analysis revealed the presence of a thin, uniform and dense
cathode electrolyte interface (CEI) flm on the surface of LNCAO cathode. An operando synchrotron
X-ray difraction (XRD) test identifed the high structural reversibility of the LNCAO cathode with a CEI
layer formed by the ADM, which efectively maintained the structural stability of the layered material.
The additive efectively inhibited the decomposition of electrolyte compositions, as confrmed by
X-ray photoelectron spectroscopy (XPS). |
| 關鍵字： | |
| 著作名稱： | Influence of Initial Porosity on the Expansion Behavior of Electrodes in Lithium-Ion Batteries |
| 年度： | 2023 |
| 類別： |
期刊論文
Journal of The Electrochemical Society
|
| 摘要： | When charging or discharging a lithium-ion-battery (LIB), lithiation or delithiation of the electrodes takes place. Especially in the case of anode active materials, lithiation often leads to a significant volume increase. The latter can cause a rearrangement of the particles. Although the volumetric changes of state-of-the-art cathode materials have been found to be smaller than for anodes, they remain relevant. The combined volumetric changes of anodes and cathodes are an important factor influencing the lifetime of LIBs. An electrochemical dilatometer was used to measure the thickness change of various electrode active materials under minimal constant pressure (≈ 16 kPa): graphite, silicon-graphite (SiG) composite electrodes, and high-voltage spinel lithium-nickel-manganese-oxide (HVS-LNMO). The influencing factors investigated included the initial porosity of the electrodes, the particle shape of graphite, and the silicon content in the case of the silicon-graphite composite electrodes. Regarding all investigated electrodes, the initial electrode porosity is shown to correlate negatively with the irreversible thickness change during the initial cycles. The thickness change in each electrode was constant over the post-formation cycles, regardless of the initial porosity. Spherical particles in graphite resulted in slightly higher thickness changes than flake-type particles. The thickness change of SiGs increased linearly with silicon content. |
| 關鍵字： | |
| 著作名稱： | Combined Effects of Citric Acid and Ascorbic Acid Used As Low-Temperature Surface Modifiers to Enhance the Cyclability of Si Anode in an Li-Ion Battery |
| 年度： | 2022 |
| 類別： |
期刊論文
Journal of Electrochemical Energy Conversion and Storage
|
| 摘要： | We successfully achieved surface modification of Si at a low temperature (150 °C) by using citric acid and ascorbic acid as surface modifiers and enhanced the electrochemical performance of a Si-based anode. A simple planetary ball-milling process followed by heat treatment over a range of temperatures (150–500 °C) was used to carry out the surface modification. This important investigation confirmed that the heat treatment temperature significantly affected the molecular structure in the modification layer, and its thickness led to a higher discharge capacity for low-temperature-modified Si compared to that in other series of high-temperature-annealed samples. Among all the surface-modified Si samples, the electrochemical performance using the M-Si 150 °C as the anode material achieved an excellent capacity of 1787 mAh g−1 after 100 charge/discharge cycles with a 75.8% retention. The same device delivered excellent rate capability, with a capacity of ∼1012 mAh g−1 (1 C) and 593 mAh g−1 (2 C) at the high-current rate. The capacity regained to ∼2012 mAh g−1 with the reversal of the current rate to 0.1 C, with a very high retention of 103%, indicating significantly enhanced strength of the modified Si anode in a lithium-ion battery. |
| 關鍵字： | silicon, surface modification, citric acid/ascorbic acid, anode material, lithium-ion batteries, batteries |
| 著作名稱： | The Role of Silicon in Silicon-Graphite Composite Electrodes Regarding Specific Capacity, Cycle Stability, and Expansion |
| 年度： | 2022 |
| 類別： |
期刊論文
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Mo-Doped SnO2 Quantum Dots Dispersed Over Reduced Graphene Oxide Sheets as an Efficient Anode Material |
| 年度： | 2022 |
| 類別： |
期刊論文
Journal of Electrochemical Energy Conversion and Storage
|
| 摘要： | We explore the effect of Mo doping over the large enhancement of electrochemical property of Mo-doped SnO2 quantum dots (3–5 nm) grown over rGO (reduced graphene oxide) sheets by a soft chemical process in ambient conditions. The composites were prepared over a range of Mo doping concentrations (0–10%) and 5% Mo doping had achieved the best energy storage characteristics. The capacity of the active material could reach ∼851 mAh g−1 (@ 78 mA g−1) in the beginning and that retained ∼89% (∼758 mAh g−1) with superior cyclic stability (100 cycles) and rate capability (506 mAh g−1 @ ∼1.5 A g−1). The addition of the reductant of 0.06 mol during the synthesis procedure led to further improvement of the capacity to ∼875 mAh g−1 (∼92% retention) and the rate capability (∼587 mAh g−1). These impressive results are ascribed to the distribution of Mo-doped SnO2 QDs, doping of Mo6+ at Sn4+ lattice sites providing more electrons for easy electrical transport, reduction of GO (graphene oxide) to rGO. Mo doping led to the decline in the charge transfer resistance (Rct) from 14.99 Ω for un-doped SnO2/rGO to 14.09 Ω (2.5%), 11.61 Ω (5%), and 11.4 Ω (10%) and promote the electrochemical property of the composite. A simple room-temperature synthesis process was used to produce Mo-doped SnO2/rGO nanocomposite and can be employed for the production of many other oxides and their composites for interesting applications. |
| 關鍵字： | Mo-Doped SnO2 Quantum Dots Dispersed Over Reduced Graphene Oxide Sheets as an Efficient Anode Material |
| 著作名稱： | Multi-Layer Graphene/SnO2 Nanocomposites as Negative Electrode Materials for Lithium-Ion Batteries |
| 年度： | 2020 |
| 類別： |
期刊論文
JOURNAL OF ELECTROCHEMICAL ENERGY CONVERSION AND STORAGE
|
| 摘要： | We report the synthesis of SnO2/multi-layer graphene nanocomposites by an easy low temperature (60 °C) electroless plating route. An aqueous suspension containing Sn(BF4)2 with multi-layer graphene is reacted at 60 °C in an acidic environment for 1 h, and Na2S2O4 is used to reduce tin ion from Sn(BF4)2. After electroless plating, the presence of SnO2 particle (15–35 nm) attached to the multi-layer graphene is confirmed by transmission electron microscopy. Tin oxide (SnO2) can be used to modify multi-layer graphene via electroless plating process decorating with oxygen-containing functional groups. It is found that the electroless plating has enhanced the electrochemical performance of SnO2 and multi-layer graphene that shows reasonably good capacity (∼243 mAh g−1 after 50 charge/discharge cycles) and high Coulombic efficiency (∼78%). |
| 關鍵字： | SnO2, nanocomposites, lithium-ion batteries, multi-layer graphene, electrochemical storage |
| 著作名稱： | Synthesis of self-assembled Hollow-Sphere ZnO/rGO Nanocomposite as Anode Materials for Lithium-Ion Batteries |
| 年度： | 2019 |
| 類別： |
期刊論文
International Journal of Electrochemical Science
|
| 摘要： | We investigate the lithium storage properties of two kinds of materials as anode for LIB: graphene oxide (GO) and self-assembled hollow-sphere zinc oxide/reduced graphene oxide (ZnO/rGO) nanocomposite. GO is obtained by Hummers method controlled by the various process parameters. The ZnO/rGO hollow sphere nanocomposite is synthesized by a low temperature (95 °C) chemical solution reaction. For ZnO/rGO composite, the capacity is increased remarkably as compared to GO sheets, and this is due to the synergistic effects of both the components in the composite. The GO acts as a conductive buffer layer that promotes the conductivity, and suppresses the volume expansion of ZnO during the charge/discharge process. ZnO/rGO hollow sphere structure nanocomposite has higher capacity 605.36
mAh g-1 , which is 4.5 times higher than GO (133.82 mAh g-1 ), after 20 cycles. The capacity variation with the charge-discharge rate of ZnO/rGO nanocomposite showed a higher capacity (299.95 mAhg-1 at 1700 mAg-1 ) than GO (20.09 mAhg-1 at 1488 mAg-1) after 32 cycles. |
| 關鍵字： | self-assemble hollow sphere structure, ZnO/rGO nanocomposite, lithium-ion batteries |
| 著作名稱： | Thermal and solid electrolyte interphase characterization of lithium-ion battery |
| 年度： | 2019 |
| 類別： |
期刊論文
Energy
|
| 摘要： | Thermal behavior and solid electrolyte interphase (SEI) are crucial topics for the development and operation of the lithium-ion battery. To investigate the thermal behavior and SEI formation in a lithiumion battery (C-LiMn0.5Ni0.3Co0.2O2), a numerical method combining the pseudo-two-dimensional electrochemical model, heat transfer model, and capacity fading model is developed. For the battery operated at a low C-rate, the ohmic heat and the reversible heat dominate the heat generation at a low state of charge (SOC) and high SOC, respectively. Alternatively, the ohmic heat is the dominant factor causing heat generation at a high C-rate. The reversible heat reaches a maximum at the SOC of 65% due to the entropic coefficient of the cathode active materials. The SEI thickness increases around 70 nm with increasing the C rate cycling. The heat generation is the bottleneck for the resistance of Liþ ion conductivity at the SCI. The heat generation of the cathode is larger than that of the anode, which is caused
by the low solid phase conductivity of the cathode. This analysis has provided useful insights into the thermal management of lithium-ion battery in the course of charging and discharging which is conducive to the development and safe operation of the battery |
| 關鍵字： | Lithium-ion battery, Electrochemical model,Heat transfer model, Capacity fade model, Heat generation, Solid electrolyte interphase film |
| 著作名稱： | Reduced graphene oxide (RGO)-SnOx (x0,1,2) nanocomposite as high performance anode material for lithium-ion batteries |
| 年度： | 2019 |
| 類別： |
期刊論文
Journal of Alloys and Compounds
|
| 摘要： | Although, metal oxide-graphene nanocomposites and their applications in Li ion battery is a subject of intense investigation over the years, the synthesis of the composite that often needs high temperature processing along with expensive equipment are the major issues to overcome. We demonstrate a facile, low cost and room temperature synthesis of SnOX (x 0,1,2) - reduced graphene oxide (RGO) nanocomposite where concurrent formation of SnO2, reduction of SnO2 to SnOx nanoparticles and graphene oxide to reduced graphene oxide takes place in one pot in-situ chemical reduction process. Concentration of the reducing agent (NaBH4, 0 mol–0.06 mol) is varied to examine the effect on the formation of the nanocomposite as well as their electrochemical performance. The RGO-SnOx nanocomposite prepared by using 0.04 mol of reducing agent reveal better Li storage performance, stable capacitance (833 mAh g−1 after 50 cycles, 767 mAh g−1 after 100 cycles, current rate 100 mA g−1), and good rate capability (481 mAh g−1 at ∼1 A g−1). The lithium ion diffusion coefficient of RGO-SnOx (0.04 mol) nanocomposite is estimated as 2.4 × 10−10 m2s−1 that is one/two order higher than other RGO-SnOx nanocomposites which promotes the Li ion transport in the composite. The synthesis procedure has a strong potential to be one of the universal method for the preparation of a variety of composites by the suitable variant in the synthesis protocol. |
| 關鍵字： | Keywords SnO2NanocompositeLithium-ion batteryReduced graphene oxide |
| 著作名稱： | (Ti+Sn)O2固溶體應用於鋰離子電池負極研究 |
| 年度： | 2012 |
| 類別： |
期刊論文
中國鑛冶工程學會會刊
|
| 摘要： | 二氧化鈦經過化學處理與燒結後形成錫/二氧化鈦複合材料，並藉由掃描電子顯微鏡與X光繞射圖譜辨認表面形貌與晶體結構。結果顯示二氧化鈦經過錫修飾表面變的較緻密且結構在煅燒後轉變為固溶體，之後將此錫/二氧化鈦複合材料進行電池特性測試，結果指出錫修飾能有效地減少二氧化鈦的第一次充放電不可逆電容量約14.6%，並使錫/二氧化鈦複合材料具有約350（mAh g^(-1)）的可逆電容量，且經50次循環後電容量仍維持在250（mAh g^(-1)）左右。 |
| 關鍵字： | 二氧化鈦、錫、鋰離子電池 |
| 著作名稱： | 聚丙烯酸修飾碳材於PC電解液中對鋰電池性能研究 |
| 年度： | 2010 |
| 類別： |
期刊論文
工程科技與教育學刊
|
| 摘要： | 鋰離子電池自問世以來，因具高工作電壓、高能量密度且無記憶效應的優勢，成爲市場上的主流。目前鋰離子電池改善方向有正極材料、電解液和負極材料。電解液以碳酸丙烯酯(PC)爲主，而負極以碳材居多。不過PC易與碳極反應，進入碳材層狀結構，進而撐開碳層與碳層之間的夾層，使得整個碳材結構崩解，影響電池特性。本實驗期望在石墨表面表面上包覆聚丙烯酸(PAA)，以改善NG碳材在充放電過程中與電解液產生的結構崩解，進而改善電池特性。 |
| 關鍵字： | 鋰離子電池、碳酸丙烯酯PC、天然石墨、聚丙烯酸PAA |
| 著作名稱： | 含烯基及硫化合物電解液添加劑對於鋰離子電池石墨材料表面特性研究 |
| 年度： | 2010 |
| 類別： |
期刊論文
工程科技與教育學刊
|
| 摘要： | 本研究以碳酸亞乙烯酯（VC）和三硫代碳酸亞乙烯酯（VTC）作為電解液添加劑進行鋰離子電池測試。並利用循環伏安法、半電池測試、電交流阻抗。由循環伏安發現隨著漸增至3％濃度的電解液添加劑，VC和VTC充分在石墨層上發展形成一層SEI膜。並以掃描式電子顯微鏡（SEM）用來觀察添加劑影響所形成的SEI膜。透過半電池測試了解電解液添加劑對於電池效能所帶來影響。結果顯示，循環壽命性能在3％濃度時VC電解液添加劑優於VTC電解液添加劑。因此我們可以推測VC和VTC充放電的過程中，在石墨上所形成的SEI膜對於循環壽命與參與反應的能力有所影響。 |
| 關鍵字： | |
| 著作名稱： | 錫硫化物修飾於碳材表面應用於鋰離子電池負極之特性研究 |
| 年度： | 2010 |
| 類別： |
期刊論文
工程科技與教育學刊
|
| 摘要： | 本研究利用以亞硫代硫酸鈉(Na2S2O4)作還原劑之無電鍍法，將具高容鋰活性物質的錫金屬微量修飾於天然石墨的表面上，以幫助鋰離子的崁入與脫崁，提升電池整體電容量及電池循環性能之穩定性。本實驗將無電鍍法修飾錫之碳材經由SEM、XRD分析材料，更進一步將粉料製備成電極，利用Coin Cell充放電循環壽命測試與交流阻抗測試等電化學方法，比較材料之電化學特性，進而調整不同的鍍浴濃度、反應時間及最佳鍍浴溫度，以期找出最佳的無電鍍修飾條件，進而改善鋰離子電池。 |
| 關鍵字： | 無電鍍、錫硫化物修飾、碳材、鋰離子電池 |
| 著作名稱： | 錫硫化物修飾奈米二氧化鈦於鋰離子電池負極之特性研究 |
| 年度： | 2010 |
| 類別： |
期刊論文
工程科技與教育學刊
|
| 摘要： | 本研究利用無電鍍法將錫硫化物修飾於市售的二氧化鈦奈米粉末，再以450℃高溫燒結1小時，應用於鋰離子電池之負極材料。此修飾法能提升電池的電容量，以高溫燒結方法去除多餘硫含量，以增加其電化學性能。將修飾微量錫之二氧化鈦材料分為高溫燒結及未燒結兩組，藉由充放電測試、循環壽命測試及放電速率測試，可進一步了解高溫燒結對於修飾錫硫化物之二氧化鈦於鋰離子電池特性影響。 |
| 關鍵字： | 無電鍍、錫硫化物、二氧化鈦、鋰離子電池 |
| 著作名稱： | 張家欽，黃政璇，劉世鈞，”聯毗啶銅錯鹽在玻璃碳電極上之吸附行為探討”，南師學報，第38期，61-76，民國九十三年。 |
| 年度： | 2004 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 劉世鈞，曾琬婷，張家欽，”鎳大環錯合物聚合膜修飾電極之穩定化及對氧之還原行為”，南師學報，第37期，63-73，民國九十二年。 |
| 年度： | 2003 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 劉世鈞，張家欽，黃政璇，”二氮菲銅錯鹽在玻璃碳電極上之電化學反應吸附行為探討”，南師學報，第36期，187-201，民國九十一年。 |
| 年度： | 2002 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 利用金離子聚合3，4-ethylenedioxythiophene（EDOT）修飾磷酸鋰鐵（LiFePO4）於鋰離子電池之特性研究 |
| 年度： | 2012 |
| 類別： |
期刊論文
國立臺南大學環境與生態學報
|
| 摘要： | 磷酸鋰鐵正極材料其工作電壓適中（3.2V）、電容量170 mAh˙g^（-1）、安全性高和原料價格低。但其缺點為導電性不佳（10^（-9） S˙cm^（-1））。故利用導電性高分子poly（3 ,4-ethylenedioxythiophene）（PEDOT）對磷酸鋰鐵正極材料表面進行修飾，以改善其電池的性能。本研究利用氧化還原方式使用不同度的Au（上標 +）當作氧化劑來聚合3,4-ethylenedioxythiophene（EDOT）單體形成PEDOT修飾於磷酸鋰鐵材料，以改善磷酸鋰鐵材料阻抗，提升鋰離子電池之循環壽命、改善高充放電速率時所損失的電容量、減少充放電所需的時間。並以熱重量分析（Thermogravimetry Analyzer，TGA）、紫外光可見光光譜分析儀（UV-visible）和掃描式電子顯微鏡（Scanning Electron Microscopy，SEM）對材料表面分析證實PEDOT成功的聚合在磷酸鋰鐵材料上。並進一步通過循環伏安法（Cyclic Voltammetry，CV）、電化學阻抗圖譜（Electrochemical Impedance Spectroscopy，EIS）、Coin Cell充放電測試、循環壽命測試等電化學方法，對於材料特性與電化學特性有提升的效果。 |
| 關鍵字： | 鋰離子電池 ； 磷酸鋰鐵 ； 導電性高分子 ； 聚（3,4－乙烯基二氧噻吩） |
| 著作名稱： | 電解液對於黃金電極吸附1,6-己烷基雙硫醇影響之研究 |
| 年度： | 2010 |
| 類別： |
期刊論文
國立臺南大學環境與生態學報
|
| 摘要： | 黃金電極表面吸附1,6-己烷基雙硫醇 (HDT) 已被廣泛應用於酵素偵測電極之酵素固定化，為瞭解電解液中離子與分子交互作用影響電極表面其吸附之穩定性，本研究利用循環伏安法 (cyclic voltammetry, CV) 和電化學阻抗分析 (electrochemical impedance spectroscopy,EIS) 偵測不同電解液影響HDT 物質吸附於黃金電極表面的特性，分別取常用的硫酸鹽類(Na2SO4) 和過氯酸鹽類 (LiClO4) 做比較，並觀察於不同電解質濃度下對吸附於黃金電極表面的HDT之影響，由研究成果可知LiClO4對於HDT-黃金電極吸附膜之影響較小，此機制建立有助於現今生醫科技之感測研究。 |
| 關鍵字： | 1,6-己烷基雙硫醇物質、循環伏安法、電化學阻抗分析 |
| 著作名稱： | 張家欽，劉世鈞，何緯倫，”淺談全球環境變遷與能源教育”，國教之友， 56卷，2期，p3-7（2005）。 |
| 年度： | 2005 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 白富升，劉世鈞，張家欽，”校園用電管理與節能教育設計”，國教之友 ， 56卷，2期，p8-11（2005）。 |
| 年度： | 2005 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 溫添進，張家欽，”電化學製氧化劑(O3,H2O2,HOCl)及其應用”，化工，42卷6期，.60-72，民國八十四年。 |
| 年度： | 1995 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 溫添進，張家欽，”臭氧之應用及其電解法製造”，化工，41卷3期，.60-71，民國八十三年。 |
| 年度： | 1994 |
| 類別： |
期刊論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 待定 |
| 年度： | 2018 |
| 類別： |
會議論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Molybdenum doped 0.5Li2MnO3-0.5LiNi0.33Mn0.33Co0.33O2 cathode preventing Surface Phase Transitions for high-voltage lithium-ion battery |
| 年度： | 2018 |
| 類別： |
會議論文
|
| 摘要： | The purpose of this study was to develop a high voltage and high stability cathode material for high capacity lithium-ion batteries. In this study, Sol-Gel synthesis was applied to synthesize the pristine and Mo-doped layered 0.5Li2MnO3-0.5LiNi0.33Mn0.33Co0.33O2 (LNMC). XPS results showed, the valence states of Mn in pure LNMC were all in Mn4+, but the valence states of Mn in Mo-doped LNMC were 2.17 % Mn3+ and 97.83 % Mn4+. The XAS results indicated the valence states of Mn and Mo increased slightly and the coordination condition of Mn and Mo had been changed at high voltage. Electrochemical measurements demonstrated that Mo-doped LNMC had a better rate capability and cycling stability in the voltage range of 2-4.8V than those of pristine LNMC. Similarly, Mo-doped LNMC exhibited higher discharge capacity and capacity-retention than pristine LNMC after 30 cycles (224 mAh/g and 83.3% vs. 169 mAh/g and 61.2 %). |
| 關鍵字： | |
| 著作名稱： | Molybdenum modifed on 0.5Li2MnO3-0.5LiNi0.33Mn0.33Co0.33O2 cathode for high-voltage lithium-ion battery |
| 年度： | 2018 |
| 類別： |
會議論文
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| 摘要： | The purpose of this study was to develop a high capacity, high voltage and high stability cathode material in the lithium-ion batteries. In this study, Sol-Gel synthesis was applied to synthesize the pristine layered 0.5Li2MnO3-0.5LiNi0.33Mn0.33Co0.33O2 (LNMC). In order to decrease structural defects, LNMC was doped with Molybdenum. X-ray photoelectron spectroscopy (XPS) was used to characterize the valence states of Mn and Mo in LNMC. X-ray absorption spectroscopy (XAS) was applied to probe the valence states and coordination environment of Mn and Mo at various charge-discharge stages. The results of XPS showed the valence states of Mn in LNMC were all Mn4+, but the valence states of Mn in Mo-doped LNMC were 2.17% Mn3+ and 97.83% Mn4+. On the other hand, the XAS results indicated the valence states of Mn and Mo increased slightly and the coordination environment of Mn and Mo had been changed at high voltage. This study found that coordination environment of Mo-doped LNMC changed fewer than pristine LNMC, implying Mo-doped LNMC had more stable electrochemical properties at high voltage. Electrochemical
measurements demonstrated that Mo-doped LNMC had a better rate capability and cycling stability in the voltage range of 2V-4.8V than those of pristine LNMC. Similarly, Mo-doped LNMC exhibited higher discharge capacity and capacity-retention than pristine LNMC after 30 cycles (269mAh/g and 83.3% vs. 276mAh/g and 61.2%). |
| 關鍵字： | |
| 著作名稱： | 1F23 Development of Si-based anode materials for Li-ion batteries 16:40 (China Steel Chemical, National Univ. of Tainan, National Cheng Kung Univ.) ○Po-ChinChen, Hsiang-YuHsu, Yuan-PingYang, Wei-ChihChen, Yi-ShiunChen, Kai-ChihHsu,Chia-ChinChang,Kuang-ZongFung |
| 年度： | 2018 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 微電網電化學儲能元件開發 |
| 年度： | 2017 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | A Comparative Study of Polyacrylic Acid and Polyvinylidene Difluoride Binders for TiO2 Anode in Lithium-Ion Batteries |
| 年度： | 2017 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Carbon coated mechanochemical Si/Cu3Si/C negative electrode materials for lithium ion battery |
| 年度： | 2017 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Development of LiFePO4 Lithium Ion Battery for Low Temperature Applications |
| 年度： | 2017 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Electrochemical Properties of P2-Na2/3[Fe1/3Mn2/3]O2 Cathode Material for Sodium Ion Batteries |
| 年度： | 2017 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Rutile TiO2 Nanorods as Lithium Storage Material with Enhanced Capacity and Good Rate Capability |
| 年度： | 2017 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Understanding the inserted sodium in spherical carbon and hard carbon electrode of sodium ion battery |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | In Situ Synchrotron X-Ray Diffraction Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | The mechanism of inserted sodium in spherical carbon electrode of sodium ion battery |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Electrodeposition of Iron‐Cobalt alloy from FeCo‐based ionic liquids |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Functional Additives for Lithium ion battery |
| 年度： | 2015 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Effect of nano sized tin composite on graphite as anode for lithium ion battery |
| 年度： | 2015 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | In-Situ X-ray Diffraction on the Lithium-Ion Migrating in Micro-Porous Separator |
| 年度： | 2015 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Ionic Liquid Mixed with Organic Solvents as an Electrolyte for LiFePo4 Battery |
| 年度： | 2015 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Effects of water based binders on lithium ion batteries with a TiO2 anode |
| 年度： | 2014 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Borane and borates compounds as electrolyte additives for LiFePO4 cathode |
| 年度： | 2013 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Improved safety and performance for Li-ion battery: Mixtures of ionic liquid and organic electrolytes |
| 年度： | 2012 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Oxysilane as electrolyte additives for lithium ion battery |
| 年度： | 2012 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Nano-(SnTi)O2 composite negative electrodes for lithium-ion batteries |
| 年度： | 2012 |
| 類別： |
會議論文
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| 摘要： | Nano-(SnTi)O2 composites synthesized by the sequential application of chemical treatment and N2 atmosphere calcination at various temperatures (450oC, 500oC and 600oC) were investigated by transmission electron microscopic (TEM), electron-dispersive spectroscopy (EDS), x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and inductively coupled plasmas (ICP). The results show that the tin amount in (SnTi)O2 composites are around 20 wt%. The SnO2 coated on the surface of TiO2 powders at 450oC treatment to form core shell structure at 450oC and the shape of (SnTi)O2 composites become granular after calcination. The concentration gradient of Sn in the TiO2 particle is increased with increasing calcination temperature. The XRD results indicate that deposit (SnTi)O2 solid solution onto TiO2 powders at 500oC and 600oC. The electrochemical characteristics of (SnTi)O2 composites were characterized by using cyclic voltammetric (CV), rate-capability, and cycle-life studies. Results show that the Nano-(SnTi)O2 composites have remarkably high capacity, high safety, high rate performance, and good cyclability for lithium ion battery. |
| 關鍵字： | Lithium-ion battery, Tin, Tin oxide, Solid solution, Pyrolysis, Titanium dioxide. |
| 著作名稱： | The effect of ionic liquid electrolyte on the cathode materials for Lithium ion battery |
| 年度： | 2012 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Nano-Tin/TiO2 composite negative electrodes for lithium-ion battery |
| 年度： | 2011 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Nano-Tin/TiO2 composite negative electrodes for lithium-ion batteries |
| 年度： | 2011 |
| 類別： |
會議論文
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| 摘要： | Nano-Tin/TiO2 composite have been prepared as anode material for lithium ion battery by chemical reduction and the nitrogen atmosphere pyrolysis technique. The nano-particle deposits were uniformly distributed on the surface of nano-TiO2 powders through the examination of SEM and TEM. The composite anode materials were characterized by using cyclic voltammetry (CV), rate capability studies and cycle life testing. Results show that the nano-Tin/TiO2 composite have remarkably high capacity, high safety, high rate performance, and good cyclability for lithium ion battery.
Although the nano-Tin/TiO2 composite have remarkably performance for lithium ion battery, but electrochemical results indicated that the composite have high irreversible capacity at first cycle. The irreversible capacity at first cycle were improved by applying four type of methods, including using electrolyte additives , different binder system (PAA and SBR), replacing the substrate of Sn/ TiO2 from TiO2 to Li2Ti3O7 and doping Li into the nano-Tin/TiO2 composite. Results show that PAA binder and the method of doping Li can reduce first irreversible capacity and keep good cycle life.
|
| 關鍵字： | |
| 著作名稱： | The effect of ionic liquid electrolytes on the cathode materials for Lithium ion battery |
| 年度： | 2011 |
| 類別： |
會議論文
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| 摘要： | It is well known that the main efforts in the development of lithium-ion batteries (LIBs) regard the portable electronic devices, trying to increase the battery power density, and the huge market of electric vehicles (EVs) and hybrid-electric vehicles (HEVs). Safety is the key-feature of LIBs. Ionic liquids (ILs) have been proposed as electrolytes for long-lived and safe LIBs, since they are non-flammability and have low volatility. The electrolyte solution comprises an ionic liquid of a bis(trifluoromethanesulfonyl)imide (TFSI) as anion and tetraethylammonium (N2222) as cation together with ethylene carbonate (EC) and dimethyl carbonate (DMC). The electrochemical behaviors of ionic liquid electrolyte on cathode materials for LIBs are investigated by cyclic voltammetry, and AC impedance. The electrochemical performance of electrolyte of ionic liquid based is worse than 1M LiPF6 EC/DMC electrolyte. The LiFePO4 cathode provides the better rate capability, cycle life test performance than LiCoO2 cathode. This result shows that the IL electrolyte influences the battery properties on different cathode materials. |
| 關鍵字： | Ionic liquid; Cathode; Lithium-ion battery; tetraethylammonium bis(trifluoromethanesulfonyl)imide (N2222–TFSI) |
| 著作名稱： | The effect of ionic liquid electrolytes on the cathode materials for Lithium ion battery |
| 年度： | 2011 |
| 類別： |
會議論文
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| 摘要： | Ionic liquids exhibit very low vapor pressure and high non-flammability properties that are of central importance in their use as safe electrolytes for large - size in lithium-ion batteries. The mixed electrolytes are based on an ionic liquid (IL) as triethylmethylammonium bis(trifluoromethylsulfonyl) amide (N1222-TFSI) and organic solvents as ethylene carbonate (EC), diethylene carbonate (DEC), ethyl methyl carbonate (EMC) and dimethyene carbonate (DMC) with LiPF6 salt. The different compositions of mixed electrolytes were prepared by adding N1222-TFSI to the different organic solvents. The specific capacity and cycling efficiency of LiFePO4 cathode of Li-ion battery with mixture of ionic liquid and organic electrolytes are investigated by coin cell tests.. The flammability of the electrolytes is examined by directly observing the flame on the surface of the electrolytes for a couple of seconds. The results of specific capacity and cycling efficiency of mixed electrolytes of different compositions of organic electrolytes are reported and discussed. |
| 關鍵字： | Ion liquids; Cathodes; Lithium-ion battery; triethylmethylammonium bis(trifluoromethylsulfonyl) amide |
| 著作名稱： | High temperature cycling performance of LiFePO4 cathode enhanced by Tris(pentafluorophenyl) borane additive |
| 年度： | 2010 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 生物可分解塑膠(PLA)產品應用之碳足跡研究 |
| 年度： | 2010 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Tin Sulfide and Tin Oxide /Graphite Composite Anodes for Lithium-ion Batteries |
| 年度： | 2010 |
| 類別： |
會議論文
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| 摘要： | Lithium ion battery is a major component for providing power in electronic equipment. Recently, the development of the high capacity anode material, many researchers focus on the metals (such as Sn, Sb). The carbon are taking the lead in anode for commercialization of Li-ion batteries, some researchers modified the tin-oxides on the carbon surface as anodes to avert the volume change of metal. The adequate amount of metal oxides on the carbon surface can improve the electrochemistry characteristics for battery application. The rules of metal oxides on
the carbon surface for Solid electrolyte interface ( SEI ) films has been studied. We introduce the tin metal with oxygen or sulfur compounds into the SEI structure to help
the XPS, FTIR surface analysis and materials analysis technique on the SEI films and to understand tin oxides and tin sulfurs how to affect Li+ intercalated/ eintercalated in surface. These modified materials are investigated by the cyclic voltammetry test, electrochemical impedance measurements, cycle life performance, coin cell tests to observe the electrochemical behaviors of tin oxides and tin sulfurs on the NG surface. The SEM, ESCA, Auger, and FTIR are applied to analysis the surface composition of SEI films. From the electrochemical behaviors and material surface analysis results, we have proved that the rules of tin oxides and tin sulfurs on SEI structure. |
| 關鍵字： | Lithium ion battery, tin oxides, tin sulfurs, solid electrolyte interface film. |
| 著作名稱： | Jane Her, Yi-Zhen Su, Chia-Chin Chang, "Effects of dispersant upon the conductive carbon and its application to LiFePO4 cathode of Li-ion batteries", The 49th battery symposium in Japan, November 5-7, 2008, RIHGA ROYAL HOTEL SAKAI, OSAKA, 3G08 (2008). |
| 年度： | 2008 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Yi Wu, Li-Chia Chen, Chia-Chin Chang, and Hsien-Chang Chang, “Development of Capillary Electrophoresis Chip with Electrochemical Detector for Detecting Histamine”, The 2nd International Meeting on Microsensors and Microsystems, National Cheng Kung University, Tainan, Taiwan, Jan. 15-18, 2006. |
| 年度： | 2006 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Shyh-Jiun Liu、Li-Chia Chen、Chia-Chin Chang ,“Electrocatalytic Activity of Boron-Doped Diamond Electrode for Methanol Oxidation in Alkaline Solution”, The 5th Asian Conference on Electrochemistry, May 09 -12, 2005, SHANGHAI, CHINA (ACEC 2005). |
| 年度： | 2005 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Hsien-Ju Tien, Chia-Chin Chang, Wan-Ting Tzeng, Shyh-Jiun Liu, “The Mechanism of methanol oxidation on pol(NiII-tetramethyldibenzotetraaza[14] annulene) film modified electrodes”, International Symposium on Organic Reactions, Kaohsiung, December 18-21 (2003). |
| 年度： | 2003 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Ten-Chin Wen and Chia-Chin Chang, “An Investigation of Thermally Prepared Electrodes for Oxygen Reduction in Alkaline Solution”, The 38th Battery Symposium in Japan, Osaka, Nov. 11-13, 1997. |
| 年度： | 1997 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Ten-Chin Wen and Chia-Chin Chang, “An Investigation of Oxygen Reduction at RuO2-Coated Titanium Electrode on Alkaline Solution”, The Electrochemical Society, Meeting Abstracts, Vol. 96-1, LOS ANGELS CALIFORNIA, May 5-10 Abstract No. 1128(1996). |
| 年度： | 1996 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang and Ten-Chin Wen, “Kinetics of Oxygen Reduction at Iridium Oxide-Coated Titanium Electrode”, 1995 ASIAN CONFERENCE ON ELECTROCHEMISTRY, Osaka, Japan(1995). |
| 年度： | 1995 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Ten-Chin Wen and Chia-Chin Chang, “Electrolytic Production of Ozone in Phosphate Solutions”, Environmental Applications of Electrochemical Technology, The 6th International Forum on Electrolysis in the Chemical Industry, Fort Lauderale, Florida November 8-12(1992) |
| 年度： | 1992 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Ten-Chin Wen and Chia-Chin Chang, “ Electrolytic Production of Ozone in Water”, ASIAN WATERQUAL 91, Shanghai, November(1991). |
| 年度： | 1991 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Electrolyte additives for lithium ion battery |
| 年度： | 2023 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | The solid electrolyte interphase layer with electrolyte additive LiPO2F2 to improve electrochemical performance on graphite electrodes for LIB |
| 年度： | 2022 |
| 類別： |
會議論文
|
| 摘要： | |
| 關鍵字： | |
| 著作名稱： | LiPO2F2 as an additive to improve electrochemical performance of graphite electrodes for LIB |
| 年度： | 2020 |
| 類別： |
會議論文
|
| 摘要： | |
| 關鍵字： | Graphite, electrolyte additive, Neutron diffraction, Lithium ion battery, solid electrolyte interphase |
| 著作名稱： | Carbon Electrode as a Negative Electrode of Sodium Ion Battery for Energy Storage Device |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Effects of Boron-based esters as an electrolyte additive on the electrochemical behavior of NMC/MGP Lithium ion batteries |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 鋰電池碳-矽複合材料粉末之EFM與CAFM成像分析 |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Multi-layer graphene/ SnO2 nanocomposites as negative electrode materials for lithium-ion batteries |
| 年度： | 2016 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Hybrid Ionic Liquid / Carbonate Electrolyte with Vinylene Carbonate Additive for LiFePO4/Li Batteries |
| 年度： | 2014 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | SnOx修飾於TiO2表面應用於鋰離子電池負極 |
| 年度： | 2012 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 水系黏著劑系統應用於磷酸鐵鋰正極材料特性 |
| 年度： | 2012 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 氧基矽烷電解液添加劑於鋰離子電池特性研究 |
| 年度： | 2012 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Functional Additives for Lithium Ion Batteries(Invited Speaker) |
| 年度： | 2010 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 陳昱淳, 蘇羽秀, 張家欽, “錫硫化物修飾奈米二氧化鈦於鋰離子電池負極之特性研究” 第二屆兩岸三地綠色材料學術研討會, 國立高雄應用科技大學 (2009). |
| 年度： | 2009 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 洪苔瑛, 林漢綸, 張家欽 “錫硫化物修飾於碳材表面應用於鋰離子電池負極之特性研究” 第二屆兩岸三地綠色材料學術研討會, 國立高雄應用科技大學 (2009). |
| 年度： | 2009 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 張家欽, 賴志昀, 鍾怡芳, 詹勗忠, “含烯基及硫化合物電解液添加劑對於鋰離子電池石墨材料表面特性” 第二屆兩岸三地綠色材料學術研討會, 國立高雄應用科技大學 (2009). |
| 年度： | 2009 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, “Functional Electrolyte Additives for Lithium Ion Batteries”, 2009年化工年會, 中興大學，Invited Speaker(2009). |
| 年度： | 2009 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Chia-Chin Chang, Ten-Chin Wen, "The mechanism of Oxygen Reduction on IrO2/Ti electrode", 第三屆氫能與燃料電池研討會, 臺南大學, FC045(2008). |
| 年度： | 2008 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 蘇羿貞, 張家欽, 何麗貞, "應用於燃料電池之奈米碳管分散技術", 第三屆氫能與燃料電池研討會, 臺南大學, FC060(2008). |
| 年度： | 2008 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 張家欽、彭詩華、林君芸、陳珉儒、翁崎勝、陳俊佑,"銅錯合物觸媒應用於白金電極氧氣還原受甲醇干擾之研究",第三屆氫能與燃料電池研討會, 臺南大學, FC073(2008). |
| 年度： | 2008 |
| 類別： |
會議論文
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| 著作名稱： | Chia-Chin Chang,Shiu-Jhong Jhan,Huang-Kai Su,Sheng-Hsiang Hsu, "Vinylene Carbonate and Vinylene trithiocarbonate as Electrolyte Additives for Lithium Ion Battery", 2008 Taiwan/Korea/Japan Chemical Engineering Conference
and 55th Taiwan Institute of Chemical Engineers Annual Conference, (2008). |
| 年度： | 2008 |
| 類別： |
會議論文
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| 著作名稱： | Tai-Ying Hung, Huang-Kai Su, Chia-Chin Chang, "Sn composites on graphite anode for lithium ion battery",2008 Taiwan/Korea/Japan Chemical Engineering Conference and 55th Taiwan Institute of Chemical Engineers Annual Conference, (2008). |
| 年度： | 2008 |
| 類別： |
會議論文
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| 著作名稱： | 王志泰，劉良力，張家欽，"旅遊人數與棲地因子對牛埔農塘鳥類分佈的影響", 2006年中華民國環境教育學術研討會,中華民國環境教育學術研討會,台中教育大學 D05(2006). |
| 年度： | 2006 |
| 類別： |
會議論文
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| 著作名稱： | 9. 王志泰、張家欽、劉良力，旅遊活動與棲地因子對生態工法營造之牛埔農塘公園鳥類分佈的影響，2005景觀論壇-永續景觀研討會論文集，中華民國景觀學會、東海大學景觀學系，台中(2005)p.272. |
| 年度： | 2005 |
| 類別： |
會議論文
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| 著作名稱： | 林東毅，李冠誼，張家欽，張翠玲， “26S Proteasome偵測系統中電解液對於黃金電極吸附HDT影響之研究” 材料年會，國立東華大學（2009）. |
| 年度： | 2009 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 蘇羽秀，陳昱淳，張家欽， “錫／二氧化鈦奈米複合材料於鋰離子電池負極之研究”，材料年會，國立東華大學（2009）. |
| 年度： | 2009 |
| 類別： |
會議論文
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| 著作名稱： | 蘇羽秀,張家欽,胡啟章,郭幸宜, "二氧化鈦負極材料於鋰離子電池之特性研究", 材料年會, (2008) |
| 年度： | 2008 |
| 類別： |
會議論文
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| 著作名稱： | 許盛翔,何麗貞,蘇羿貞,周慶文,張家欽, "分散劑對導電碳之分散性於磷酸鋰鐵正極製作之鋰離子電池特性研究", 材料年會 （2008） |
| 年度： | 2008 |
| 類別： |
會議論文
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| 著作名稱： | Li-Chia Chen, Chia-Chin Chang, Shyh-Jiun Liu, Hsien-Ju Tien, “The Electrooxidation of Formaldehyde at Boron-Doped Diamond Electrode” ，中國化學年會，高雄中山大學(2005) ANA0296。 |
| 年度： | 2005 |
| 類別： |
會議論文
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| 著作名稱： | 陳立家，張家欽，張憲彰，”The detection of Organic Substrates by boron-doped Diamond Electrode”，The 11th Symposium on Sensing Technology,28 May 2005, Chia-Yi, Taiwan. |
| 年度： | 2005 |
| 類別： |
會議論文
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| 著作名稱： | 3. Chia-Chin Chang, Yen-Yu Lee, Shyh-Jiun Liu, Hsien-Ju Tien, Li-Jane Her, “2,2-Dimethoxy-Propane as Electrolyte Additives for Lithium Ion batteries” 中國化學年會，高雄中山大學(2005) AC0028。 |
| 年度： | 2005 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 陳永松，張家欽，劉世鈞，何麗貞，”鋰離子二次電池負極碳材修飾銻金屬之研究”，中國化學年會，高雄中山大學(2005) AC0029。 |
| 年度： | 2005 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 許朝陽，劉世鈞，張家欽，何麗貞，”鋰離子二次電池陽極材料MGP修飾奈米錫金屬之製備與性質”，中國化學年會，高雄中山大學(2005) AC0958。 |
| 年度： | 2005 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 彭詩華，劉世鈞，張家欽，”銅錯合物觸媒應用在白金電極氧氣還原受甲醇干擾之研究” ，中國化學年會，高雄中山大學(2005) OC0780。 |
| 年度： | 2005 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | Li-Chia Chen(陳立家), Chia-Chin Chang(張家欽), and Shyh-Jiun Liu(劉世鈞), “Anodic Oxidation Behaviors of Formaldehyde at Boron-Doped Diamond Electrode”, 中國化學工程年會，聯合大學，苗栗(2005)。 |
| 年度： | 2005 |
| 類別： |
會議論文
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| 著作名稱： | Li-Chia Chen、Chia-Chin Chang、Shyh-Jiun Liu,”Electrochemical properties of Methanol and Benzoalcohol on Boron-Doped Diamond Electrode”, 中國化學工程年會，南台大學(2004)。 |
| 年度： | 2004 |
| 類別： |
會議論文
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| 著作名稱： | Chia-Chin Chang、Li-Jane Her、 Jin-Long Hong、Shyh-Jiun Liu, Electrocopolymerization of Thiophene and 3,4-Ethylenedioxythiophene on Stainless Steel Electrode as a Cathode for Lithium Ion Batteries, 中國化學工程年會，南台大學(2004)。 |
| 年度： | 2004 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 陳立家，劉世鈞，曾琬婷，張家欽，田憲儒”甲醇氧化在鎳大環錯合物修飾電極的毒化行為探討”，中國化學年會，中壢中原大學(2003)。 |
| 年度： | 2003 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 黃政璇，張家欽，劉世鈞，”含氮銅錯合物在玻璃碳電極表面電化學吸附行為探討” ，中國化學年會，中壢中原大學(2003)。 |
| 年度： | 2003 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 黃政璇，張家欽，劉世鈞，”含氮銅錯合物電催化氧氣還原反應之研究”，中國化學年會，中壢中原大學(2003)。 |
| 年度： | 2003 |
| 類別： |
會議論文
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| 摘要： | |
| 關鍵字： | |
| 著作名稱： | 陳靖毅，劉世鈞，張家欽”氧氣還原在銅錯合物觸媒中甲醇之干擾性研究”，中國化學年會，中壢中原大學(2003)。 |
| 年度： | 2003 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 莊展安，劉世鈞，張家欽，朱聖緣，”含不同中心金屬的?青素之光電特性研究”，中國化學年會，中壢中原大學(2003)。 |
| 年度： | 2003 |
| 類別： |
會議論文
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| 著作名稱： | 陳思聖，張家欽，溫添進，”2,5-二甲氧苯胺與2,2-雙苯胺共聚導電高分子合成及物性研究”，材料年會，p.684-685(2002) 。 |
| 年度： | 2002 |
| 類別： |
會議論文
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| 著作名稱： | 溫添進，趙碩，張家欽，”電解製造過氯酸鈉中陽極PbO2之結構變化”，材料年會，p.352-353(1994)高雄，中山大學。 |
| 年度： | 1994 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 溫添進，張家欽，趙碩，閻志中，”氧化劑對於PbO2腐蝕之影響”，材料年會，p.684-685(1994) 高雄，中山大學。 |
| 年度： | 1994 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 電動機車與儲能系統應用之材料與電池 |
| 年度： | 2019 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | LiNi0.5Mn1.5O4之應用 |
| 年度： | 2019 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | The behaviors of lithium and sodium ions in negative electrodes for metal ion batteries |
| 年度： | 2018 |
| 類別： |
會議論文
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| 摘要： | |
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| 著作名稱： | 鋰離子在負極材料之擴散行為 |
| 年度： | 2019 |
| 類別： |
會議論文
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