國立臺南大學教師基本資料

基本資料
姓名 張家欽
系所 綠色能源科技學系
職稱 教授
校內分機
傳真 (06)2602205
辦公室/研究室 能源材料實驗室 / 鋰離子電池中心
E-mail ccchang@mail.nutn.edu.tw
網址 http://www.nutn.edu.tw/lithium/
專長/研究領域 電化學,儲能材料開發,鋰離子電池,燃料電池材料開發
 

畢業學校國別主修學門學位修業期間
成功大學中華民國化學工程研究所碩士1990 - 1992
成功大學中華民國化學工程研究所博士1992 – 1996

服務機關部門 / 系所職稱服務期間
能元科技研發部經理1998~2003
國立台南師範學院環境生態研究助理教授2003/8~2004/8
財團法人自強工業科學基金會 能源材料講師2003~2004
國立臺南大學環境生態研究助理教授2004/8~2006/8
國立臺南大學環境與能源學系副教授2006/8~2009/7
聚和國際股份有限公司 顧問2008-
國立臺南大學綠色能源科技學系教授2009/7~

著作
名稱Ten-Chin Wen and Chia-Chin Chang, “Effect of Additives in the Preparation of PbO2 Deposits on the Electrocatalytic Activity”, Surface Modification Technologies V, Edited by T. S. Sudarshan and J. F. Braza, the Institute of Materials p.611-617(1992). (Book)
年度1992
類別專書
摘要 
關鍵字 
名稱Ten-Chin Wen and Chia-Chin Chang, “Electrolytic Production of Ozone in Phosphate Solutions Using an Orthogonal-Array Experimentation”, J. CIChE, 23 (1992)387.
年度1992
類別期刊論文
摘要 
關鍵字 
名稱溫添進,張家欽,”臭氧之應用及其電解法製造”,化工,41卷3期,.60-71,民國八十三年。
年度1994
類別期刊論文
摘要 
關鍵字 
名稱溫添進,張家欽,”電化學製氧化劑(O3,H2O2,HOCl)及其應用”,化工,42卷6期,.60-72,民國八十四年。
年度1995
類別期刊論文
摘要 
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名稱溫添進,張家欽, “一種電解製造臭氧的方法”,專利字號078318號。
年度1995
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang and Ten-Chin Wen, “Oxygen Reduction at IrO2-Coated Titanium Electrodes in Alkaline Solution”, Bulletin of Electrochemistry, 11(1995)430.
年度1995
類別期刊論文
摘要 
關鍵字 
名稱Ten-Chin Wen and Chia-Chin Chang, “The Structural of Changes of PbO2 anodes during Ozone Evolution”, J. Electrochem. Soc., 140(1995)2764.
年度1995
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang and Ten-Chin Wen, “Kinetics of Oxyhen Reduction at IrO2-Coated Titanium Electrodes in Alkaline Solution”, J. Electrochem. Soc., 143(1996)1473.
年度1996
類別期刊論文
摘要 
關鍵字 
名稱Yat-June Li, Chia-Chin Chang, and Ten-Chin Wen, “Application of Statistical Experimental Strategies to H2O2 Production on Au/Graphite in Alkaline Solution”, Ind. Eng. Chem. Res., 35(1996)4767.
年度1996
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang and Ten-Chin Wen, “Oxygen Reduction at RuO2-Coated Titanium Electrodes in Alkaline Solution”, J. Appl. Electrochem., 27(1997)355.
年度1997
類別期刊論文
摘要 
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名稱Chia-Chin Chang, Ten-Chin Wen and Hsien-Ju Tien, “Oxygen Reduction at Oxide-derived Pd Electrodes in Alkaline Solution”, Electrochimica Acta, 42 (1997)557.
年度1997
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang and Ten-Chin Wen, “An Investigation of Thermally Prepared Electrodes for Oxygen Reduction in Alkaline Solution,” Materials Chemistry and Physics, 47(1997) 203.
年度1997
類別期刊論文
摘要 
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名稱Yat –June Li, Chia-Chin Chang, and Ten-Chin Wen, “A Mixture Design Approach to Ir-Pt-Au Ternary Thermally Prepared Electrodes for Oxygen Reduction in Alkaline Solution”, J. Appl. Electrochem., 27(1997)227.
年度1997
類別期刊論文
摘要 
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名稱劉世鈞,張家欽,黃政璇,”二氮菲銅錯鹽在玻璃碳電極上之電化學反應吸附行為探討”,南師學報,第36期,187-201,民國九十一年。
年度2002
類別期刊論文
摘要 
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名稱劉世鈞,曾琬婷,張家欽,”鎳大環錯合物聚合膜修飾電極之穩定化及對氧之還原行為”,南師學報,第37期,63-73,民國九十二年。
年度2003
類別期刊論文
摘要 
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名稱Shyh-Jiun Liu, Cheng-Hsua Huang, and Chia-Chin Chang, “Oxygen Reduction in Phosphate Solution with the Cu(II) Complex of 1,10-phenanthroline at Glassy Carbon Electrode”, Materials Chemistry and Physics, 82(2003)551.
年度2003
類別期刊論文
摘要 
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名稱張家欽,黃政璇,劉世鈞,”聯毗啶銅錯鹽在玻璃碳電極上之吸附行為探討”,南師學報,第38期,61-76,民國九十三年。
年度2004
類別期刊論文
摘要 
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名稱張家欽,劉世鈞,何緯倫,”淺談全球環境變遷與能源教育”,國教之友, 56卷,2期,p3-7(2005)。
年度2005
類別期刊論文
摘要 
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名稱白富升,劉世鈞,張家欽,”校園用電管理與節能教育設計”,國教之友 , 56卷,2期,p8-11(2005)。
年度2005
類別期刊論文
摘要 
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名稱Chia-Chin Chang, Li-Jane Her, Jin-Long Hong, “Copolymer from Electropolymerization of Thiophene and 3,4-Ethylenedioxythiophene and its Use as Cathode for Lithium Ion Battery”, Electrochim. Acta, 50(2005)4461-4468.
年度2005
類別期刊論文
摘要 
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名稱Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Shu-Fang Hsu, Shan-Shan Chou, Pau-Yee Lin, Hsien-Chang Chang,Anodic oxidation Behaviors of Methanol and Benzyl Alcohol at Boron-Doped Diamond Electrode, Electrochemistry, 73(2005) 1014.
年度2005
類別期刊論文
摘要 
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名稱Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Hsien-Ju Tien, and Hsien-Chang Chang, “Anodic Oxidation Behaviors of Formaldehyde at Boron-Doped Diamond Electrode”, Journal of the Chinese Chemical Society,53 (2006) 839.
年度2006
類別期刊論文
摘要 
關鍵字 
名稱Li-Jane Her, Jin-Long Hong, Chia-Chin Chang, Preparation and Electrochemical Characterizations of Poly(3,4-dioxyethlenethiophene)/LiCoO2 Composite Cathode in Lithium-Ion Battery, J. Power Sources, 157(2006)457.
年度2006
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Hsien-Chang Chang, “The electro-oxidation of formaldehyde at boron-doped diamond electrode”, Analytical Letters, 39(2006)2581.
年度2006
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang and Ten-Chin Wen, "Kinetics and Mechanism of Oxygen Reduction at Hydrous Oxide Film-Covered Platinum Electrode in Alkaline Solution", Electrochimica Acta, 52(2006)623-629.
年度2006
類別期刊論文
摘要 
關鍵字 
名稱Li-Jane Her, Jin-Long Hong, Chia-Chin Chang, "Preparation and Electrochemical Characterizations of Poly(3,4-dioxyethylenethiophene)/LiCoO2-Ketjenblack Composite Cathode in Lithium-Ion Battery", J. Power Sources, 161(2006)1247.
年度2006
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang, Li-Chia Chen, Shyh-Jiun Liu, Hsien-Chang Chang, "Investigation of electro-oxidation of methanol and benzyl alcohol at boron-doped diamond electrode: Evidence the mechanism for fouling film formation", Journal of Physical Chemistry: B, 110(2006)19426.
年度2006
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang,Li-Chia Chen,Hsien-Chang Chang,Hsien-Ju Tien, "Electrocatalytic Activity of Methanol oxidation at Boron-Doped Diamond Electrode in Alkaline Solution", Journal of the Chinese Chemical Society, 53 (2006)1269.
年度2006
類別期刊論文
摘要 
關鍵字 
名稱Chien-Hsin Yang,Shyh-Jiun Liu, Chia-Chin Chang, Li-Ying Lin, "Electrochromic devices based on copolymers of 3-Trimethoxysilanylpropyl-N-aniline-2,5-Dimethoxyaniline" Journal of Electroanalytical Chemistry 590 (2006) 161–172.
年度2006
類別期刊論文
摘要 
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名稱Chia-Chin Chang *, Shyh-Jiun Liu, Jeng-Jang Wu, Chien-Hsin Yang “Nano-tin oxide/tin particles on the graphite surface as an anode material for lithium-ion batteries”, Journal of Physic Chemistry: C, 111(2007) 16423-16427.
年度2007
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang, Li-Jane Her, Li-Chia Chen, Yen-Yu Lee, Shyh-Jiun Liu, Hsien-Ju Tien, “2,2-Dimethoxy-Propane as Electrolyte Additive for Lithium Ion Batteries” Journal of Power Sources, 163 (2007)1059.
年度2007
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang, Li-Jane Her, Ti-Kang Chen, Li-Chia Chen, Jin-Long Hong, "The influence of different electrode fabrication methods and poly(vinylidene fluoride) binders on the anode electrode dimension stability and cyclability in lithium-ion batteries", Journal of New Materials for Electrochemical Systems, 11 (2008) 43-47.
年度2008
類別期刊論文
摘要 
關鍵字 
名稱Li-Chia Chen, Chia-Chin Chang, Hsien-Chang Chang, “Electrochemical Oxidation of Histidine at an Anodic Oxidized Boron-Doped Diamond Electrode in Neutral Solution”, Electrochimica Acta, 53 (2008) 2883–2889.
年度2008
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang, “Sb-coated Mesophase Graphite Powder as Anode Material for Lithium-Ion Batteries”, Journal of Power Sources, 175 (2008) 874-880.
年度2008
類別期刊論文
摘要 
關鍵字 
名稱Chi-Chang Lin, Li-Chia Chen, Chien-Hao Huang, Shinn-Jyh Ding, Chia-Chin Chang,Hsien-Chang Chang, "Development of the multi-functionalized gold nanoparticles with Electrochemical-based immunoassay for protein A detection" Journal of Electroanalytical Chemistry 619–620 (2008) 39–45.
年度2008
類別期刊論文
摘要 
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名稱Chien-Hsin Yang,Feng-Jiin Liu, Liang-Ren Huang, Tzong-Liu Wang, Wen-Churng Lin, Mitsunobu Sato, Cheng-Ho Chen, Chia-Chin Chang, "The application of triphenylamine-based hole-transporting materials in electrochromic devices" Journal of Electroanalytical Chemistry 617 (2008) 101–110.
年度2008
類別期刊論文
摘要 
關鍵字 
名稱Chia-Chin Chang, Wei-Lun Ho, Li-Jane Her, Jin-Long Hong, Shyh-Jiun Liu, Chien-Hsin Yang, “Poly(3-methylthiophene) as a Conductive Additive on LiCoO2 Composite Cathode in Lithium-Ion Battery”, Journal of New Materials for Electrochemical Systems, 11(2008) 49-54(SCI)
年度2008
類別期刊論文
摘要 
關鍵字 
名稱The methanol adsorption behavior on platinum/ poly(2,5-dimethoxyaniline) composites for application in methanol sensing
年度2008
類別期刊論文
摘要The behavior of methanol adsorption on platinum/poly(2,5-dimethoxyaniline) (Pt/PDMA) composite is investigated using UV–vis spectroscopy (UV–vis) and open circuit potential (OCP). The results of scanning electron microscopy and energy dispersive spectroscopy are used to verify the uniform dispersion of Pt in PDMA. The Fourier transform infrared spectra and OCP results revealed that Pt particles interact with PDMA through the electron-rich nitrogen sites, influencing the oxidation state of PDMA. A model is proposed for themethanol adsorption on Pt particles which changes the interaction between Pt andPDMA. With the proposed model,methanol concentration can be discerned using potentiometric measurements. The results of this study can be applied to methanol sensors for direct methanol fuel cells.
關鍵字Direct methanol fuel cells, Methanol adsorption, Methanol sensing, Platinum/poly(2,5-dimethoxyaniline) composites
名稱Chia-Chin Chang*, Ten-Chin Wen, Chien-Hsin Yang, Yung-Der Juang, "Influence of Calcination Temperature of IrO2/Ti Electrodes on Oxygen Reduction", Materials Chemistry and Physics, inpress.
年度2008
類別期刊論文
摘要 
關鍵字 
名稱Influence of Calcination Temperature of IrO2/Ti Electrodes on Oxygen Reduction
年度2009
類別期刊論文
摘要IrO2-coated titanium plate electrocatalysts prepared by a dip-coating method (IrO2/Ti) with different calcination temperatures are characterized by scanning electron microscope, X-ray diffraction and Xray photoelectron spectroscopy. The electrocatalytic behavior of the oxygen reduction reaction (ORR) is evaluated by cyclic voltammetry and galvanostatic electrolysis in 1 moldm−3 KOH solution. The effects of calcination temperature on the oxygen reduction pathway are examined. Galvanostatic electrolysis results showthat the reaction pathway on the IrO2/Ti electrode prepared at high calcination temperature is mainly a two-electron pathway producing H2O2. It is observed that higher calcination temperatures produce: a more uniform fault-free surface; reduced levels of Cl contamination (residual Cl presumably from incomplete IrCl3 decomposition during the coating process); higher levels of rutile character of the IrO2 layer; lower hydration levels. It is confirmed that ORR electrocatalytic behavior on highly hydrated IrO2 is better than on slightly hydrated IrO2.
關鍵字Heat treatment, Oxygen reduction reaction, Oxides, Adsorption, X-ray photo-emission spectroscopy
名稱Tris(pentafluorophenyl) borane as an electrolyte additive for LiFePO4 battery
年度2009
類別期刊論文
摘要The effects of tris(pentafluorophenyl) borane (TPFPB) additive in electrolyte at the LiFePO4 cathode on the high temperature capacity fading were investigated by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), cyclability, SEM and Fourier transform infrared (FTIR). According to the study results, tris(pentafluorophenyl) borane has the ability to improve the cycle performance of LiFePO4 at high temperature. LiFePO4 electrodes cycled in the electrolyte without the TPFPB additive show a significant increase in charge transfer resistance by EIS analysis. SEM and FTIR disclose evidence of surface morphology change and solid electrolyte interface (SEI) formation. FTIR investigation shows various functional groups are found on the cathode material surface after high temperature cycling tests. The results showed an obvious improvement of high temperature cycle performance for LiFePO4 cathode material due to the TPFPB additive. The observed improved cycling performance and improved lithium ion transport are attributed to decreased LiF content in the SEI film.
關鍵字Lithium-ion battery, Tris(pentafluorophenyl) borane, Electrolyte additive, LiFePO4
名稱Tris(pentafluorophenyl) borane as an electrolyte additive to improve the high temperature cycling performance of LiFePO4 cathode
年度2009
類別期刊論文
摘要The capacity fading of LiFePO4 batteries using 1.2 mol dm−3 LiPF6 ethylene carbonate/dimethyl carbonate electrolyte with trispentafluorophenylborane TPFPB additive at 60°C is investigated by cyclic voltammetry, cyclability, electrochemical impedance spectroscopy EIS, and scanning electron microscopy SEM. The cyclability results show that the LiFePO4–Li cell with the TPFPB additive electrolytes exhibits high discharge capacity and good cycling performance at 60°C. The LiFePO4 electrode cycled at 60°C without the TPFPB additive shows a significant increase in charge-transfer resistance by EIS analysis. The TPFPB additive in the electrolyte reduces the difference in the charge-transfer resistance before and after 100 cycles at elevated temperatures. SEM results show that after 100 cycles at 60°C in an electrolyte without TPFPB additive, the LiFePO4 electrode forms a visible material on the electrode surface. The observed material is presumably related with capacity fading in the LiFePO4–Li cell. The results indicate that TPFPB in the electrolyte prevents the formation of the observed material on the electrode, reduces charge-transfer resistance, and enhances cycling performance of the LiFePO4–Li cells at 60°C.
關鍵字
名稱聚丙烯酸修飾碳材於PC電解液中對鋰電池性能研究
年度2010
類別期刊論文
摘要鋰離子電池自問世以來,因具高工作電壓、高能量密度且無記憶效應的優勢,成爲市場上的主流。目前鋰離子電池改善方向有正極材料、電解液和負極材料。電解液以碳酸丙烯酯(PC)爲主,而負極以碳材居多。不過PC易與碳極反應,進入碳材層狀結構,進而撐開碳層與碳層之間的夾層,使得整個碳材結構崩解,影響電池特性。本實驗期望在石墨表面表面上包覆聚丙烯酸(PAA),以改善NG碳材在充放電過程中與電解液產生的結構崩解,進而改善電池特性。
關鍵字鋰離子電池、碳酸丙烯酯PC、天然石墨、聚丙烯酸PAA
名稱含烯基及硫化合物電解液添加劑對於鋰離子電池石墨材料表面特性研究
年度2010
類別期刊論文
摘要本研究以碳酸亞乙烯酯(VC)和三硫代碳酸亞乙烯酯(VTC)作為電解液添加劑進行鋰離子電池測試。並利用循環伏安法、半電池測試、電交流阻抗。由循環伏安發現隨著漸增至3%濃度的電解液添加劑,VC和VTC充分在石墨層上發展形成一層SEI膜。並以掃描式電子顯微鏡(SEM)用來觀察添加劑影響所形成的SEI膜。透過半電池測試了解電解液添加劑對於電池效能所帶來影響。結果顯示,循環壽命性能在3%濃度時VC電解液添加劑優於VTC電解液添加劑。因此我們可以推測VC和VTC充放電的過程中,在石墨上所形成的SEI膜對於循環壽命與參與反應的能力有所影響。
關鍵字
名稱錫硫化物修飾於碳材表面應用於鋰離子電池負極之特性研究
年度2010
類別期刊論文
摘要本研究利用以亞硫代硫酸鈉(Na2S2O4)作還原劑之無電鍍法,將具高容鋰活性物質的錫金屬微量修飾於天然石墨的表面上,以幫助鋰離子的崁入與脫崁,提升電池整體電容量及電池循環性能之穩定性。本實驗將無電鍍法修飾錫之碳材經由SEM、XRD分析材料,更進一步將粉料製備成電極,利用Coin Cell充放電循環壽命測試與交流阻抗測試等電化學方法,比較材料之電化學特性,進而調整不同的鍍浴濃度、反應時間及最佳鍍浴溫度,以期找出最佳的無電鍍修飾條件,進而改善鋰離子電池。
關鍵字無電鍍、錫硫化物修飾、碳材、鋰離子電池
名稱錫硫化物修飾奈米二氧化鈦於鋰離子電池負極之特性研究
年度2010
類別期刊論文
摘要本研究利用無電鍍法將錫硫化物修飾於市售的二氧化鈦奈米粉末,再以450℃高溫燒結1小時,應用於鋰離子電池之負極材料。此修飾法能提升電池的電容量,以高溫燒結方法去除多餘硫含量,以增加其電化學性能。將修飾微量錫之二氧化鈦材料分為高溫燒結及未燒結兩組,藉由充放電測試、循環壽命測試及放電速率測試,可進一步了解高溫燒結對於修飾錫硫化物之二氧化鈦於鋰離子電池特性影響。
關鍵字無電鍍、錫硫化物、二氧化鈦、鋰離子電池
名稱電解液對於黃金電極吸附1,6-己烷基雙硫醇影響之研究
年度2010
類別期刊論文
摘要黃金電極表面吸附1,6-己烷基雙硫醇 (HDT) 已被廣泛應用於酵素偵測電極之酵素固定化,為瞭解電解液中離子與分子交互作用影響電極表面其吸附之穩定性,本研究利用循環伏安法 (cyclic voltammetry, CV) 和電化學阻抗分析 (electrochemical impedance spectroscopy,EIS) 偵測不同電解液影響HDT 物質吸附於黃金電極表面的特性,分別取常用的硫酸鹽類(Na2SO4) 和過氯酸鹽類 (LiClO4) 做比較,並觀察於不同電解質濃度下對吸附於黃金電極表面的HDT之影響,由研究成果可知LiClO4對於HDT-黃金電極吸附膜之影響較小,此機制建立有助於現今生醫科技之感測研究。
關鍵字1,6-己烷基雙硫醇物質、循環伏安法、電化學阻抗分析
名稱Effects of Dispersant on the Conductive Carbon for LiFePO4 Cathode
年度2011
類別期刊論文
摘要Carbon-based electrically conductive particles (cECP) are commonly used to reduce interparticle resistance in Li-ion batteries, but cECP tend to flocculate in the dense slurries used to fabricate electrodes. Herein, a novel dispersant limits flocculated cECP particle size and improves cECP dispersion. The increased cECP efficacy allows reduced addition of carbon to the battery, thereby increasing the ratio of active material to conductive material and increasing volumetric energy density. With/without dispersant LiFePO4/ketjenblack cathodes are examined by scanning electron microscopy (SEM), slurry viscosity, electrochemical redox behavior, electrochemical impendence spectroscopy (EIS) and charge/discharge cycling performance. Discharge capacity, durability and resistance are better for the with-dispersant LiFePO4 cathode. EIS shows reduced interfacial impedance and increased cycling performance for the with-dispersant electrode. SEM shows smooth distribution of nano-scale particles of consistent size with dispersant use. Without dispersant, the cECP particles are micro-scale, with high variability in size and location. It is seen that a good cECP dispersant in the initial electrode slurry improves Li-ion battery performance, primarily because of a more cohesive cECP network between the active material particles.
關鍵字Lithium-ion battery, Dispersant, LiFePO4, Conductive additive.
名稱Vinylene carbonate and vinylene trithiocarbonate as electrolyte additives forlithium ion battery
年度2011
類別期刊論文
摘要Vinylene carbonate (VC) and vinylene trithiocarbonate (VTC) are studied as electrolyte additives in two kinds of electrolytes: (1) propylene carbonate (PC) and diethyl carbonate (DEC) (1:2 by weight) 1 mol dm?3 LiPF6; (2) ethylene carbonate (EC) and DEC (1:2 by weight) 1 mol dm?3 LiPF6. Characterization is performed by cyclic voltammetry, impedance spectroscopy, scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectroscopy (XPS) and half cell tests. Cyclic life is better in either electrolyte with VC than either electrolyte with/without VTC. SEM shows VC and VTC both form well developed passivation films on the graphite anode, but the films with VTC are thicker than with VC. EIS shows the VTC films have significantly higher charge transfer resistance. The VTC film in PC fails to protect against exfoliation. XPS indicates VTC has different reaction pathways in PC relative to EC. In EC/DEC, VTC forms polymeric C–O–C-like components and sulfide species (C–S–S–C, S and C–S–C). In PC/DEC, VTC does not form polymeric species, instead forming a film mainly containing LiF and Li2S. It appears that a thinner polymeric film is preferential. The specific data herein are of interest, and the general conclusions may help development of improved additives for enhanced Li-ion battery performance.
關鍵字Vinylene carbonate (VC); Vinylene trithiocarbonate (VTC); Electrolyte additive; Lithium ion battery
名稱The electrochemical method for detecting 26S proteasome
年度2011
類別期刊論文
摘要Alkyl- and phenyl-substituted borate anion receptors, triphenyl borate (TPB) and trimethyl borate (TMB), are investigated as electrolyte additives in lithium ion batteries (LiFePO4 cathode, 1 M LiPF6 EC-DMC 1:1 electrolyte) at 25 and 60 C. TPB shows formation of a thick surface/electrolyte interface (SEI) which hampers ion flow and does not protect the electrode from degradation. Although useful at 25 C, TPB at 60 C results in only 7% capacity after 100 cycles, whereas 0.1 M TMB results in 53% capacity. TMB performance improves with increasing concentration. TMB also suppresses thermal decomposition of the electrolyte and formation of the SEI film.
關鍵字26S proteasome; 1,6-hexanedithiol; Cyclic voltammetry; Electrochemical Impedance spectroscopy.
名稱Effects of Chemical Dispersant and Wet Mechanical Milling Methods on ConductiveCarbon Dispersion and Rate Capabilities of LiFePO4 Batteries
年度2012
類別期刊論文
摘要The dispersion state of conductive carbons in the cathodes of lithium ion batteries fabricated with a dispersant and with/without mechanical milling are considered with regard to the batteries’ charge–discharge properties. Suspensions of Ketjen black (KB, EC 300J and EC 600JD) are dispersed in an organic solvent. Ball milling is then performed, modifying the particle sizes and structures. Results show improved dispersion but with collateral reduction of both maximum and average particle sizes. The more fragile EC 600JD, after ballmilling, is broken into more small segments than EC 300J, but with segment density high enough for loose coupling to form networks. Therefore, the electron conduction of EC600JD after ball milling is better than EC 300J. The high-rate discharge capacity of EC600JD after ball milling is also better than that of EC 300J. However, rate capabilities decrease with increasing milling time.
關鍵字Conductive carbon; Lithium ion batteries; Dispersion; Mechanical milling; Hollow structure.
名稱Compatibility of LiFePO4 and LiNi1/3Mn1/3Co1/3O2 Electrode Materials with Quaternary-ammonium Based Ionic Liquid Mixed with Organic Solvent Electrolyte System
年度2012
類別期刊論文
摘要Ionic liquids (ILs) have been proposed as electrolytes for long-lived and safe LIBs, since they are nonflammability and have low volatility. The interactions between of cathodes (as olivine LiFePO4 or layered LiNi1/3Mn1/3Co1/3O2 (NMC)) and ionic liquid mixed with organic solvent electrolyte were investigated by cyclic voltammetry, electrochemical impedance spectroscopy (EIS), coin cell test, and scanning electron microscope (SEM). The mixed electrolyte contains ethylene carbonate (EC), dimethyl carbonate (DMC) and ionic liquid such as bis(trifluoromethanesulfonyl)imide (TFSI) and tetraethylammonium (N2222). The results show that the LiFePO4 cathode in this mixed electrolyte had better cycling performance than the NMC cathode.
關鍵字Conductive carbon; Lithium ion batteries; Dispersion; Mechanical milling; Hollow structure
名稱Trimethyl borate and triphenyl borate as electrolyte additives for LiFePO4 cathode with enhanced high temperature performance
年度2012
類別期刊論文
摘要Alkyl- and phenyl-substituted borate anion receptors, triphenyl borate (TPB) and trimethyl borate (TMB), are investigated as electrolyte additives in lithium ion batteries (LiFePO4 cathode, 1 M LiPF6 EC-DMC 1:1 electrolyte) at 25 and 60 °C. TPB shows formation of a thick surface/electrolyte interface (SEI) which hampers ion flow and does not protect the electrode from degradation. Although useful at 25 °C, TPB at 60 °C results in only 7% capacity after 100 cycles, whereas 0.1 M TMB results in 53% capacity. TMB performance improves with increasing concentration. TMB also suppresses thermal decomposition of the electrolyte and formation of the SEI film.
關鍵字
名稱(Ti+Sn)O2固溶體應用於鋰離子電池負極研究
年度2012
類別期刊論文
摘要二氧化鈦經過化學處理與燒結後形成錫/二氧化鈦複合材料,並藉由掃描電子顯微鏡與X光繞射圖譜辨認表面形貌與晶體結構。結果顯示二氧化鈦經過錫修飾表面變的較緻密且結構在煅燒後轉變為固溶體,之後將此錫/二氧化鈦複合材料進行電池特性測試,結果指出錫修飾能有效地減少二氧化鈦的第一次充放電不可逆電容量約14.6%,並使錫/二氧化鈦複合材料具有約350(mAh g^(-1))的可逆電容量,且經50次循環後電容量仍維持在250(mAh g^(-1))左右。
關鍵字二氧化鈦、錫、鋰離子電池
名稱利用金離子聚合3,4-ethylenedioxythiophene(EDOT)修飾磷酸鋰鐵(LiFePO4)於鋰離子電池之特性研究
年度2012
類別期刊論文
摘要磷酸鋰鐵正極材料其工作電壓適中(3.2V)、電容量170 mAh˙g^(-1)、安全性高和原料價格低。但其缺點為導電性不佳(10^(-9) S˙cm^(-1))。故利用導電性高分子poly(3 ,4-ethylenedioxythiophene)(PEDOT)對磷酸鋰鐵正極材料表面進行修飾,以改善其電池的性能。本研究利用氧化還原方式使用不同度的Au(上標 +)當作氧化劑來聚合3,4-ethylenedioxythiophene(EDOT)單體形成PEDOT修飾於磷酸鋰鐵材料,以改善磷酸鋰鐵材料阻抗,提升鋰離子電池之循環壽命、改善高充放電速率時所損失的電容量、減少充放電所需的時間。並以熱重量分析(Thermogravimetry Analyzer,TGA)、紫外光可見光光譜分析儀(UV-visible)和掃描式電子顯微鏡(Scanning Electron Microscopy,SEM)對材料表面分析證實PEDOT成功的聚合在磷酸鋰鐵材料上。並進一步通過循環伏安法(Cyclic Voltammetry,CV)、電化學阻抗圖譜(Electrochemical Impedance Spectroscopy,EIS)、Coin Cell充放電測試、循環壽命測試等電化學方法,對於材料特性與電化學特性有提升的效果。
關鍵字鋰離子電池 ; 磷酸鋰鐵 ; 導電性高分子 ; 聚(3,4-乙烯基二氧噻吩)
名稱Electrochemical method for detecting ATP by 26S proteasome modified gold electrode
年度2013
類別期刊論文
摘要Electrochemical detection for adenosine-5’-triphosphate (ATP) is developed using a 26S proteasome modified gold electrode. In this method, the 26S proteasome is self-assembled onto the surface of a gold electrode, forming a 26S-gold electrode probe which can detect ATP. When the 26S-gold electrode reacts with a solution without ATP, the 26S proteasome on the electrode surface separates into 20S proteasome and PA700/19S subcomplexes, the properties of surface charges of 26S-gold electrode inhibiting electrolyte/electrode electron transmission. When ATP is present in the solution, the 26S proteasome selfassembles via ATP binding, the surface of 26S-gold electrode is turned into electroneutrality, and allows electrolyte/electrode electron transmission in proportion to the amount of ATP present. This mechanism is tested for electrochemical detection of ATP, with experimental results showing that the redox currents change with changing ATP concentrations in a linear fashion. ATP concentration can be determined over a range from 0.5 to 2.0 mM by linear sweep voltammetry. Moreover, the proposed method is successfully applied to the recognition and quantification of ATP in pig plasma.
關鍵字ATP, Electrochemical assay, 26S proteasome, Linear sweep voltammetry
名稱Maleic-anhydride-grafted ketjen black as the alternative carbon additive for LiFePO4 cathode
年度2013
類別期刊論文
摘要tKetjen black (KB) has a large specific surface area and is potentially more effective as the cathode conduc-tive additive. However, large KB flakes often overlay together to form thick stacks. In order to overcomethis problem, maleic anhydride (MA) was grafted onto the KB surface by a plasma-induced method. Sucha MA-KB additive was found to have a more homogeneous distribution in the LiFePO4cathode, whichresulted in a reduction in the electrical resistivity and electrode polarization. As the consequence, greatlyimproved cell performance was achieved, including higher capacity, higher discharge voltage, higher ratecapability, longer cycle lifetime, and a much flatter discharge curve. Detailed analysis on the dischargecurves and the electrochemical impedance spectroscopy showed that although both the electrical resis-tivity and electrode polarization were reduced by the better distribution of the MA-KB additive, thereduction in electrode polarization was more important in cutting the capacity loss.
關鍵字Lithium-iron phosphate, Li-ion battery, Ketjen black, Maleic anhydridea
名稱Rutile-type (Ti,Sn)O2 nanorods as efficient anode materials toward its lithium storage capabilities
年度2013
類別期刊論文
摘要A series of rutile-type (Ti,Sn)O2 solid solutions with nanorod architecture were successfully synthesized in this study by varying their calcination temperatures of tin-modified titanium dioxide (Sn/TiO2) nanocomposites under a nitrogen atmosphere. During the delithiation process, the (Ti,Sn)O2 nanorods obtained at 500 C delivered a specific capacity of about 300 mA h g1 and showed minimal capacity fading even at a high current density of 3 A g1.
關鍵字
名稱Effects of Styrene-Butadiene Rubber/Carboxymethylcellulose (SBR/CMC) and Polyvinylidene Difluoride (PVDF) Binders on Low Temperature Lithium Ion Batteries
年度2013
類別期刊論文
摘要Effects of styrene-butadiene rubber/carboxymethylcellulose (SBR/CMC) and polyvinylidene difluoride (PVDF) binders on the electrochemical characteristics of a type of microsize MCMB (mesocarbon microbeads) anode (SMA) at low temperature are investigated by cold/heat shock testing, differential scanning calorimetry, scanning electron microscopy, electrochemical impedance spectroscopy, coin cell testing and 18650 full cell testing. Under low temperature conditions and compared to the SMA electrode with a SBR/CMC binder, the SMA electrode with a PVDF binder has lower impedance, lower charge transfer resistance, better rate capability and superior cycleability.
關鍵字
名稱(Sn-Ti)O2 nanocomposites for high-capacity and high-rate lithium-ion storage
年度2013
類別期刊論文
摘要(Sn-Ti)O2 solid solution nanoparticles (denoted (Sn-Ti)O2-500) are prepared by application of one step of chemical treatment followed by calcination in N2 at 500°C for 2h. Transmission electron microscopic (TEM) observations reveal a nanoparticle shape change from needle-like to rod-like after heat treatment. Formation of a (Sn-Ti)O2 solid solution is confirmed by X-ray diffraction (XRD) analysis. The electrochemical properties of the (Sn-Ti)O2 solid solution are studied by cyclic voltammetric and coin cell tests. Electrochemical property results show that (Sn-Ti)O2-500 delivers a specific capacity of about 300mAhg?1, excellent cycle-life performance and high rate-capability during the delithiation process. Inductively coupled plasma results indicate a Sn content in (Sn-Ti)O2-500 of about 10.1% tin to titanium. The promising electrochemical characteristics of (Sn-Ti)O2-500 appear well suited for high-power negative electrodes of lithium ion batteries.[Copyright &y& Elsevier]
關鍵字
名稱Sputtered copper coating on silicon/graphite composite anodefor lithium ion batteries
年度2014
類別期刊論文
摘要A sputtered copper coating on a silicon/graphite composite is investigated as an anode material for lithium ion batteries (LIBs). Characterization of the material has been performed by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). Results show that the thickness of the copper on the nano-Si/graphite composite anode is controlled by the duration of copper sputtering. A sputtered copper coating of approximately 12 nm thickness improves the rate capacity, maximum energy density and the elevated temperature cycling performance of LIBs with silicon/graphite anodes. The presented results confirm that the modification provided by sputtered Cu to the morphology of the solid/electrolyte interface of the anode surface is of interest to the next generation of high performance LIBs.
關鍵字Lithium ion battery, Silicon based anode, Sputtering
名稱Real-time investigation on the influences of vanadium additives to the structural and chemical state evolutions of LiFePO4 for enhancing the electrochemical performance of lithium-ion battery
年度2014
類別期刊論文
摘要The influences of adding vanadium to the structure evolution and electrochemical performance of LiFePO4 are systematically investigated by in-situ X-ray powder diffraction and X-ray absorption near edge structure spectroscopy. The results indicate that the addition of a small amount of vanadium (less than at 1%) significantly reduces the formation of non-crystalline (highly disordered) triphylite and remnant heterosite phases in the cathode of battery especially at the rate capability higher than 0.5C. The cycle stability of LiFePO4 cathode with vanadium additive after 80 cycles is improved by 14.9% compared to that without vanadium additive. Such an enhancement could be attributed to the ion diffusion kinetics being improved and inactive triphylite being reduced by the supervalent-vanadium additive in cathode during electrochemical redox cycles.
關鍵字Lithium iron phosphate, X-ray powder diffraction, X-ray absorption near edge structure, Vanadium Lithium ion battery
名稱Mixture of Ionic Liquid and Organic Carbonate as an Electrolyte for LiFePO4 Battery
年度2016
類別期刊論文
摘要In the interest of expanding the available options for safe and inexpensive electrolyte in lithium ion batteries, we examined a novel electrolyte consisting of 30% IL (triethylmethylammonium bis(trifluoromethylsulfonyl)imide, N1222-TFSI) mixed with 70% commercial carbonate electrolyte (EC/DMC 1:1 by wt%, 0.78 mol kg-1 LiPF6) to form a hybrid electrolyte. The hybrid electrolyte failed to ignite after exposure to flame, a demonstration of high thermal stability. The aluminum corrosion is inhibited in N1222-TFSI mixed carbonate electrolyte, while the N-methyl-N-propylpyrrolidinium TFSI mixed carbonate electrolyte experienced serious pitting corrosion. The electrolyte has been observed with the LiFePO4 as positive electrode and the mesophase graphite as negative electrode in 18650 full cells. The electrochemical properties of hybrid electrolyte for the LiFePO4 electrode at 25oC and 60oC showed improved performance at high temperature in comparison to commercial electrolyte EC/DMC (1:1 by wt%) 0.78 mol kg-1 LiPF6. Vinylene carbonate (VC) as electrolyte additive in hybrid electrolyte at 2% addition was found to enhance the cycling performance at 25oC and 60oC, however a decrease in cell performance was observed at -10oC.
關鍵字lithium-ion batteries, vinylene carbonate, ionic liquid, triethylmethylammonium bis(trifluoromethylsulfonyl) amide
名稱Lithiation-induced crystal restructuring of hydrothermally prepared Sn/TiO2 nanocrystallite with substantially enhanced capacity and cycling performance for lithium-ion battery
年度2016
類別期刊論文
摘要A Sn-doped TiO2 nanocrystallite with the composition of Sn0.1Ti0.9O2 was prepared by hydrothermal co-precipitation followed by thermal annealing at 600 °C for 2 hours. Results combining high-resolution transmission electron microscopy, in situ XRD, ex situ XAS, and electrochemical impedance spectroscopy indicate that Sn0.1Ti0.9O2 underwent restructuring to give Sn-substituted TiO2 (Sn to Ti sites) by a lithiation reaction at 0.1C in a lithium-ion battery. The capacity and cyclability of Sn0.1Ti0.9O2 were increased by ∼73% (to ∼598 mA h g−1) and ∼17.4% compared with those of TiO2 (∼345 mA h g−1 and ∼22%) at 0.1C until the 250th cycle. Our results proved that these improvements were caused by the self-aligned formation of Sn–Ti oxide and the subsequent formation of a SnLix local alloy at Ti sites.
關鍵字
名稱Facile, low temperature synthesis of SnO2/reduced graphene oxide nanocomposite as anode material for lithium-ion batteries
年度2017
類別期刊論文
摘要We demonstrate a facile, single step, low temperature and energy efficient strategy for the synthesis of SnO2-reduced graphene oxide (RGO) nanocomposite where the crystallization of SnO2 nanoparticles and the reduction of graphene oxide takes place simultaneously by an in situ chemical reduction process. The electrochemical property of the SnO2-RGO composite prepared by using low concentrations of reducing agent shows better Li storage performance, good rate capability (378 mAh g−1 at 3200 mA g−1) and stable capacitance (522 mAh g−1 after 50 cycles). Increasing the reductant concentration lead to crystallization of high concentration of SnO2 nanoparticle aggregation and degrade the Li ion storage property.
關鍵字SnO2, Nanocomposite, Lithium-ion battery, Reduced graphene oxide
名稱The mechanism of the sodiation and desodiation in Super P carbon electrode for sodium-ion battery
年度2017
類別期刊論文
摘要The sodiation and desodiation of sodium (Na) into the Super-P carbon anode material were investigated using electrochemical analyses, high-resolution transmission electron microscopy (HRTEM), and neutron powder diffraction (NPD). In the sodiated Super-P carbon, sodium is stored both in the graphite interlayer space of carbon nano-particles and pores between the particles. Sodium metal clusters found in micro-pores between the carbon particles are responsible for the large irreversible capacity of the Super-P electrode. The graphite interlayer distance increases on sodiation from 3.57 Å to two distinct values of ∼3.84 and 4.41 Å. The mechanism of the process is discussed.
關鍵字Sodium-ion battery, Anode, Super P, carbon, Neutron powder diffraction
名稱Synthesis of MnOx/reduced graphene oxide nanocomposite as an anode electrode for lithium-ion batteries
年度2017
類別期刊論文
摘要We report the high performance of the manganese oxide/reduced graphene oxide (MnOx/rGO) nanocomposite as an anode electrode of a lithium-ion battery. The composite is synthesized by a low temperature (83 °C) chemical solution reaction, and shows relatively high specific capacities (660 mAh g−1) after 50 cycles. For MnOx/rGO composites, the cycling stability is increased remarkably as compared to that seen with individual MnOx, and this is due to the synergistic effects of both the components in the composite. The rGO acts as a conductive buffer layer that suppresses the volume change of MnOx, and simultaneously promotes the conductivity of MnOx. The functional groups of graphene oxide facilitate MnOx formation at low temperature, and this retains the MnOx-graphene oxide connection, thus improving the capacity and cycling stability.
關鍵字MnO2; Reduced graphene oxide; Anode materials; Li-ion batteries
名稱The synergistic effects of combining the high energy mechanical milling and wet milling on Si negative electrode materials for lithium ion battery
年度2017
類別期刊論文
摘要The submicro-sized and nanostructured Si aggregated powder is prepared by combinational routes of high energy mechanical milling (HEMM) and wet milling. Milled Si powder is investigated by particle size analyzer, SEM, TEM, XPS and XRD as well as the control ones. Its electrode is also investigated by in situ XRD and electrochemical performance. Morphology reveals that combining the high energy mechanical milling and wet milling not only fracture primary Si particles but also form submicro-sized Si aggregates constructed by amorphous and nanocrystalline phases. Moreover, XPS shows that wet milling in ethanol trigger Sisingle bondOsingle bondCH2CH3 bonding on Si surface might enhance the SEI formation. In situ XRD analysis shows negative electrode made of submicro-sized Si aggregated powder can effectively suppress formation of crystalline Li15Si4 during lithiation and delithiation due to amorphous and nanocrystalline construction. Thus, the submicro-sized Si powder with synergistic effects combining the high energy mechanical milling and wet milling in ethanol as negative electrode performs better capacity retention.
關鍵字Lithium-ion battery, Anode, Si, High energy mechanical milling, Wet milling
名稱Ten-Chin Wen and Chia-Chin Chang, “ Electrolytic Production of Ozone in Water”, ASIAN WATERQUAL 91, Shanghai, November(1991).
年度1991
類別研討會
摘要 
關鍵字 
名稱Ten-Chin Wen and Chia-Chin Chang, “Electrolytic Production of Ozone in Phosphate Solutions”, Environmental Applications of Electrochemical Technology, The 6th International Forum on Electrolysis in the Chemical Industry, Fort Lauderale, Florida November 8-12(1992)
年度1992
類別研討會
摘要 
關鍵字 
名稱溫添進,趙碩,張家欽,”電解製造過氯酸鈉中陽極PbO2之結構變化”,材料年會,p.352-353(1994)高雄,中山大學。
年度1994
類別研討會
摘要 
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名稱溫添進,張家欽,趙碩,閻志中,”氧化劑對於PbO2腐蝕之影響”,材料年會,p.684-685(1994) 高雄,中山大學。
年度1994
類別研討會
摘要 
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名稱Chia-Chin Chang and Ten-Chin Wen, “Kinetics of Oxygen Reduction at Iridium Oxide-Coated Titanium Electrode”, 1995 ASIAN CONFERENCE ON ELECTROCHEMISTRY, Osaka, Japan(1995).
年度1995
類別研討會
摘要 
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名稱Ten-Chin Wen and Chia-Chin Chang, “An Investigation of Oxygen Reduction at RuO2-Coated Titanium Electrode on Alkaline Solution”, The Electrochemical Society, Meeting Abstracts, Vol. 96-1, LOS ANGELS CALIFORNIA, May 5-10 Abstract No. 1128(1996).
年度1996
類別研討會
摘要 
關鍵字 
名稱Ten-Chin Wen and Chia-Chin Chang, “An Investigation of Thermally Prepared Electrodes for Oxygen Reduction in Alkaline Solution”, The 38th Battery Symposium in Japan, Osaka, Nov. 11-13, 1997.
年度1997
類別研討會
摘要 
關鍵字 
名稱陳思聖,張家欽,溫添進,”2,5-二甲氧苯胺與2,2-雙苯胺共聚導電高分子合成及物性研究”,材料年會,p.684-685(2002) 。
年度2002
類別研討會
摘要 
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名稱陳立家,劉世鈞,曾琬婷,張家欽,田憲儒”甲醇氧化在鎳大環錯合物修飾電極的毒化行為探討”,中國化學年會,中壢中原大學(2003)。
年度2003
類別研討會
摘要 
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名稱黃政璇,張家欽,劉世鈞,”含氮銅錯合物在玻璃碳電極表面電化學吸附行為探討” ,中國化學年會,中壢中原大學(2003)。
年度2003
類別研討會
摘要 
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名稱黃政璇,張家欽,劉世鈞,”含氮銅錯合物電催化氧氣還原反應之研究”,中國化學年會,中壢中原大學(2003)。
年度2003
類別研討會
摘要 
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名稱陳靖毅,劉世鈞,張家欽”氧氣還原在銅錯合物觸媒中甲醇之干擾性研究”,中國化學年會,中壢中原大學(2003)。
年度2003
類別研討會
摘要 
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名稱莊展安,劉世鈞,張家欽,朱聖緣,”含不同中心金屬的?青素之光電特性研究”,中國化學年會,中壢中原大學(2003)。
年度2003
類別研討會
摘要 
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名稱Hsien-Ju Tien, Chia-Chin Chang, Wan-Ting Tzeng, Shyh-Jiun Liu, “The Mechanism of methanol oxidation on pol(NiII-tetramethyldibenzotetraaza[14] annulene) film modified electrodes”, International Symposium on Organic Reactions, Kaohsiung, December 18-21 (2003).
年度2003
類別研討會
摘要 
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名稱Li-Chia Chen、Chia-Chin Chang、Shyh-Jiun Liu,”Electrochemical properties of Methanol and Benzoalcohol on Boron-Doped Diamond Electrode”, 中國化學工程年會,南台大學(2004)。
年度2004
類別研討會
摘要 
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名稱Chia-Chin Chang、Li-Jane Her、 Jin-Long Hong、Shyh-Jiun Liu, Electrocopolymerization of Thiophene and 3,4-Ethylenedioxythiophene on Stainless Steel Electrode as a Cathode for Lithium Ion Batteries, 中國化學工程年會,南台大學(2004)。
年度2004
類別研討會
摘要 
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名稱陳立家,張家欽,張憲彰,”The detection of Organic Substrates by boron-doped Diamond Electrode”,The 11th Symposium on Sensing Technology,28 May 2005, Chia-Yi, Taiwan.
年度2005
類別研討會
摘要 
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名稱3. Chia-Chin Chang, Yen-Yu Lee, Shyh-Jiun Liu, Hsien-Ju Tien, Li-Jane Her, “2,2-Dimethoxy-Propane as Electrolyte Additives for Lithium Ion batteries” 中國化學年會,高雄中山大學(2005) AC0028。
年度2005
類別研討會
摘要 
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名稱陳永松,張家欽,劉世鈞,何麗貞,”鋰離子二次電池負極碳材修飾銻金屬之研究”,中國化學年會,高雄中山大學(2005) AC0029。
年度2005
類別研討會
摘要 
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名稱許朝陽,劉世鈞,張家欽,何麗貞,”鋰離子二次電池陽極材料MGP修飾奈米錫金屬之製備與性質”,中國化學年會,高雄中山大學(2005) AC0958。
年度2005
類別研討會
摘要 
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名稱彭詩華,劉世鈞,張家欽,”銅錯合物觸媒應用在白金電極氧氣還原受甲醇干擾之研究” ,中國化學年會,高雄中山大學(2005) OC0780。
年度2005
類別研討會
摘要 
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名稱Li-Chia Chen(陳立家), Chia-Chin Chang(張家欽), and Shyh-Jiun Liu(劉世鈞), “Anodic Oxidation Behaviors of Formaldehyde at Boron-Doped Diamond Electrode”, 中國化學工程年會,聯合大學,苗栗(2005)。
年度2005
類別研討會
摘要 
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名稱Shyh-Jiun Liu、Li-Chia Chen、Chia-Chin Chang ,“Electrocatalytic Activity of Boron-Doped Diamond Electrode for Methanol Oxidation in Alkaline Solution”, The 5th Asian Conference on Electrochemistry, May 09 -12, 2005, SHANGHAI, CHINA (ACEC 2005).
年度2005
類別研討會
摘要 
關鍵字 
名稱Li-Chia Chen, Chia-Chin Chang, Shyh-Jiun Liu, Hsien-Ju Tien, “The Electrooxidation of Formaldehyde at Boron-Doped Diamond Electrode” ,中國化學年會,高雄中山大學(2005) ANA0296。
年度2005
類別研討會
摘要 
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名稱9. 王志泰、張家欽、劉良力,旅遊活動與棲地因子對生態工法營造之牛埔農塘公園鳥類分佈的影響,2005景觀論壇-永續景觀研討會論文集,中華民國景觀學會、東海大學景觀學系,台中(2005)p.272.
年度2005
類別研討會
摘要 
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名稱王志泰,劉良力,張家欽,"旅遊人數與棲地因子對牛埔農塘鳥類分佈的影響", 2006年中華民國環境教育學術研討會,中華民國環境教育學術研討會,台中教育大學 D05(2006).
年度2006
類別研討會
摘要
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名稱Chia-Yi Wu, Li-Chia Chen, Chia-Chin Chang, and Hsien-Chang Chang, “Development of Capillary Electrophoresis Chip with Electrochemical Detector for Detecting Histamine”, The 2nd International Meeting on Microsensors and Microsystems, National Cheng Kung University, Tainan, Taiwan, Jan. 15-18, 2006.
年度2006
類別研討會
摘要 
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名稱蘇羽秀,張家欽,胡啟章,郭幸宜, "二氧化鈦負極材料於鋰離子電池之特性研究", 材料年會, (2008)
年度2008
類別研討會
摘要 
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名稱許盛翔,何麗貞,蘇羿貞,周慶文,張家欽, "分散劑對導電碳之分散性於磷酸鋰鐵正極製作之鋰離子電池特性研究", 材料年會 (2008)
年度2008
類別研討會
摘要 
關鍵字 
名稱Chia-Chin Chang, Ten-Chin Wen, "The mechanism of Oxygen Reduction on IrO2/Ti electrode", 第三屆氫能與燃料電池研討會, 臺南大學, FC045(2008).
年度2008
類別研討會
摘要 
關鍵字 
名稱蘇羿貞, 張家欽, 何麗貞, "應用於燃料電池之奈米碳管分散技術", 第三屆氫能與燃料電池研討會, 臺南大學, FC060(2008).
年度2008
類別研討會
摘要 
關鍵字 
名稱張家欽、彭詩華、林君芸、陳珉儒、翁崎勝、陳俊佑,"銅錯合物觸媒應用於白金電極氧氣還原受甲醇干擾之研究",第三屆氫能與燃料電池研討會, 臺南大學, FC073(2008).
年度2008
類別研討會
摘要 
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名稱Chia-Chin Chang,Shiu-Jhong Jhan,Huang-Kai Su,Sheng-Hsiang Hsu, "Vinylene Carbonate and Vinylene trithiocarbonate as Electrolyte Additives for Lithium Ion Battery", 2008 Taiwan/Korea/Japan Chemical Engineering Conference and 55th Taiwan Institute of Chemical Engineers Annual Conference, (2008).
年度2008
類別研討會
摘要 
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名稱Tai-Ying Hung, Huang-Kai Su, Chia-Chin Chang, "Sn composites on graphite anode for lithium ion battery",2008 Taiwan/Korea/Japan Chemical Engineering Conference and 55th Taiwan Institute of Chemical Engineers Annual Conference, (2008).
年度2008
類別研討會
摘要 
關鍵字 
名稱Jane Her, Yi-Zhen Su, Chia-Chin Chang, "Effects of dispersant upon the conductive carbon and its application to LiFePO4 cathode of Li-ion batteries", The 49th battery symposium in Japan, November 5-7, 2008, RIHGA ROYAL HOTEL SAKAI, OSAKA, 3G08 (2008).
年度2008
類別研討會
摘要 
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名稱林東毅,李冠誼,張家欽,張翠玲, “26S Proteasome偵測系統中電解液對於黃金電極吸附HDT影響之研究” 材料年會,國立東華大學(2009).
年度2009
類別研討會
摘要
關鍵字
名稱蘇羽秀,陳昱淳,張家欽, “錫/二氧化鈦奈米複合材料於鋰離子電池負極之研究”,材料年會,國立東華大學(2009).
年度2009
類別研討會
摘要
關鍵字
名稱陳昱淳, 蘇羽秀, 張家欽, “錫硫化物修飾奈米二氧化鈦於鋰離子電池負極之特性研究” 第二屆兩岸三地綠色材料學術研討會, 國立高雄應用科技大學 (2009).
年度2009
類別研討會
摘要
關鍵字
名稱洪苔瑛, 林漢綸, 張家欽 “錫硫化物修飾於碳材表面應用於鋰離子電池負極之特性研究” 第二屆兩岸三地綠色材料學術研討會, 國立高雄應用科技大學 (2009).
年度2009
類別研討會
摘要
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名稱張家欽, 賴志昀, 鍾怡芳, 詹勗忠, “含烯基及硫化合物電解液添加劑對於鋰離子電池石墨材料表面特性” 第二屆兩岸三地綠色材料學術研討會, 國立高雄應用科技大學 (2009).
年度2009
類別研討會
摘要
關鍵字
名稱Chia-Chin Chang, “Functional Electrolyte Additives for Lithium Ion Batteries”, 2009年化工年會, 中興大學,Invited Speaker(2009).
年度2009
類別研討會
摘要
關鍵字
名稱Functional Additives for Lithium Ion Batteries(Invited Speaker)
年度2010
類別研討會
摘要
關鍵字
名稱Tin Sulfide and Tin Oxide /Graphite Composite Anodes for Lithium-ion Batteries
年度2010
類別研討會
摘要Lithium ion battery is a major component for providing power in electronic equipment. Recently, the development of the high capacity anode material, many researchers focus on the metals (such as Sn, Sb). The carbon are taking the lead in anode for commercialization of Li-ion batteries, some researchers modified the tin-oxides on the carbon surface as anodes to avert the volume change of metal. The adequate amount of metal oxides on the carbon surface can improve the electrochemistry characteristics for battery application. The rules of metal oxides on the carbon surface for Solid electrolyte interface ( SEI ) films has been studied. We introduce the tin metal with oxygen or sulfur compounds into the SEI structure to help the XPS, FTIR surface analysis and materials analysis technique on the SEI films and to understand tin oxides and tin sulfurs how to affect Li+ intercalated/ eintercalated in surface. These modified materials are investigated by the cyclic voltammetry test, electrochemical impedance measurements, cycle life performance, coin cell tests to observe the electrochemical behaviors of tin oxides and tin sulfurs on the NG surface. The SEM, ESCA, Auger, and FTIR are applied to analysis the surface composition of SEI films. From the electrochemical behaviors and material surface analysis results, we have proved that the rules of tin oxides and tin sulfurs on SEI structure.
關鍵字Lithium ion battery, tin oxides, tin sulfurs, solid electrolyte interface film.
名稱High temperature cycling performance of LiFePO4 cathode enhanced by Tris(pentafluorophenyl) borane additive
年度2010
類別研討會
摘要
關鍵字
名稱生物可分解塑膠(PLA)產品應用之碳足跡研究
年度2010
類別研討會
摘要
關鍵字
名稱Nano-Tin/TiO2 composite negative electrodes for lithium-ion batteries
年度2011
類別研討會
摘要Nano-Tin/TiO2 composite have been prepared as anode material for lithium ion battery by chemical reduction and the nitrogen atmosphere pyrolysis technique. The nano-particle deposits were uniformly distributed on the surface of nano-TiO2 powders through the examination of SEM and TEM. The composite anode materials were characterized by using cyclic voltammetry (CV), rate capability studies and cycle life testing. Results show that the nano-Tin/TiO2 composite have remarkably high capacity, high safety, high rate performance, and good cyclability for lithium ion battery. Although the nano-Tin/TiO2 composite have remarkably performance for lithium ion battery, but electrochemical results indicated that the composite have high irreversible capacity at first cycle. The irreversible capacity at first cycle were improved by applying four type of methods, including using electrolyte additives , different binder system (PAA and SBR), replacing the substrate of Sn/ TiO2 from TiO2 to Li2Ti3O7 and doping Li into the nano-Tin/TiO2 composite. Results show that PAA binder and the method of doping Li can reduce first irreversible capacity and keep good cycle life.
關鍵字
名稱The effect of ionic liquid electrolytes on the cathode materials for Lithium ion battery
年度2011
類別研討會
摘要It is well known that the main efforts in the development of lithium-ion batteries (LIBs) regard the portable electronic devices, trying to increase the battery power density, and the huge market of electric vehicles (EVs) and hybrid-electric vehicles (HEVs). Safety is the key-feature of LIBs. Ionic liquids (ILs) have been proposed as electrolytes for long-lived and safe LIBs, since they are non-flammability and have low volatility. The electrolyte solution comprises an ionic liquid of a bis(trifluoromethanesulfonyl)imide (TFSI) as anion and tetraethylammonium (N2222) as cation together with ethylene carbonate (EC) and dimethyl carbonate (DMC). The electrochemical behaviors of ionic liquid electrolyte on cathode materials for LIBs are investigated by cyclic voltammetry, and AC impedance. The electrochemical performance of electrolyte of ionic liquid based is worse than 1M LiPF6 EC/DMC electrolyte. The LiFePO4 cathode provides the better rate capability, cycle life test performance than LiCoO2 cathode. This result shows that the IL electrolyte influences the battery properties on different cathode materials.
關鍵字Ionic liquid; Cathode; Lithium-ion battery; tetraethylammonium bis(trifluoromethanesulfonyl)imide (N2222–TFSI)
名稱The effect of ionic liquid electrolytes on the cathode materials for Lithium ion battery
年度2011
類別研討會
摘要Ionic liquids exhibit very low vapor pressure and high non-flammability properties that are of central importance in their use as safe electrolytes for large - size in lithium-ion batteries. The mixed electrolytes are based on an ionic liquid (IL) as triethylmethylammonium bis(trifluoromethylsulfonyl) amide (N1222-TFSI) and organic solvents as ethylene carbonate (EC), diethylene carbonate (DEC), ethyl methyl carbonate (EMC) and dimethyene carbonate (DMC) with LiPF6 salt. The different compositions of mixed electrolytes were prepared by adding N1222-TFSI to the different organic solvents. The specific capacity and cycling efficiency of LiFePO4 cathode of Li-ion battery with mixture of ionic liquid and organic electrolytes are investigated by coin cell tests.. The flammability of the electrolytes is examined by directly observing the flame on the surface of the electrolytes for a couple of seconds. The results of specific capacity and cycling efficiency of mixed electrolytes of different compositions of organic electrolytes are reported and discussed.
關鍵字Ion liquids; Cathodes; Lithium-ion battery; triethylmethylammonium bis(trifluoromethylsulfonyl) amide
名稱Nano-Tin/TiO2 composite negative electrodes for lithium-ion battery
年度2011
類別研討會
摘要
關鍵字
名稱Oxysilane as electrolyte additives for lithium ion battery
年度2012
類別研討會
摘要
關鍵字
名稱Improved safety and performance for Li-ion battery: Mixtures of ionic liquid and organic electrolytes
年度2012
類別研討會
摘要
關鍵字
名稱The effect of ionic liquid electrolyte on the cathode materials for Lithium ion battery
年度2012
類別研討會
摘要
關鍵字
名稱SnOx修飾於TiO2表面應用於鋰離子電池負極
年度2012
類別研討會
摘要
關鍵字
名稱水系黏著劑系統應用於磷酸鐵鋰正極材料特性
年度2012
類別研討會
摘要
關鍵字
名稱氧基矽烷電解液添加劑於鋰離子電池特性研究
年度2012
類別研討會
摘要
關鍵字
名稱Nano-(SnTi)O2 composite negative electrodes for lithium-ion batteries
年度2012
類別研討會
摘要Nano-(SnTi)O2 composites synthesized by the sequential application of chemical treatment and N2 atmosphere calcination at various temperatures (450oC, 500oC and 600oC) were investigated by transmission electron microscopic (TEM), electron-dispersive spectroscopy (EDS), x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and inductively coupled plasmas (ICP). The results show that the tin amount in (SnTi)O2 composites are around 20 wt%. The SnO2 coated on the surface of TiO2 powders at 450oC treatment to form core shell structure at 450oC and the shape of (SnTi)O2 composites become granular after calcination. The concentration gradient of Sn in the TiO2 particle is increased with increasing calcination temperature. The XRD results indicate that deposit (SnTi)O2 solid solution onto TiO2 powders at 500oC and 600oC. The electrochemical characteristics of (SnTi)O2 composites were characterized by using cyclic voltammetric (CV), rate-capability, and cycle-life studies. Results show that the Nano-(SnTi)O2 composites have remarkably high capacity, high safety, high rate performance, and good cyclability for lithium ion battery.
關鍵字Lithium-ion battery, Tin, Tin oxide, Solid solution, Pyrolysis, Titanium dioxide.
名稱Borane and borates compounds as electrolyte additives for LiFePO4 cathode
年度2013
類別研討會
摘要
關鍵字
名稱Effects of water based binders on lithium ion batteries with a TiO2 anode
年度2014
類別研討會
摘要
關鍵字
名稱Hybrid Ionic Liquid / Carbonate Electrolyte with Vinylene Carbonate Additive for LiFePO4/Li Batteries
年度2014
類別研討會
摘要
關鍵字
名稱Ionic Liquid Mixed with Organic Solvents as an Electrolyte for LiFePo4 Battery
年度2015
類別研討會
摘要
關鍵字
名稱Functional Additives for Lithium ion battery
年度2015
類別研討會
摘要
關鍵字
名稱Effect of nano sized tin composite on graphite as anode for lithium ion battery
年度2015
類別研討會
摘要
關鍵字
名稱In-Situ X-ray Diffraction on the Lithium-Ion Migrating in Micro-Porous Separator
年度2015
類別研討會
摘要
關鍵字
名稱The mechanism of inserted sodium in spherical carbon electrode of sodium ion battery
年度2016
類別研討會
摘要
關鍵字
名稱Electrodeposition of Iron‐Cobalt alloy from FeCo‐based ionic liquids
年度2016
類別研討會
摘要
關鍵字
名稱Understanding the inserted sodium in spherical carbon and hard carbon electrode of sodium ion battery
年度2016
類別研討會
摘要
關鍵字
名稱In Situ Synchrotron X-Ray Diffraction Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries
年度2016
類別研討會
摘要
關鍵字
名稱Carbon Electrode as a Negative Electrode of Sodium Ion Battery for Energy Storage Device
年度2016
類別研討會
摘要
關鍵字
名稱Effects of Boron-based esters as an electrolyte additive on the electrochemical behavior of NMC/MGP Lithium ion batteries
年度2016
類別研討會
摘要
關鍵字
名稱鋰電池碳-矽複合材料粉末之EFM與CAFM成像分析
年度2016
類別研討會
摘要
關鍵字
名稱Multi-layer graphene/ SnO2 nanocomposites as negative electrode materials for lithium-ion batteries
年度2016
類別研討會
摘要
關鍵字
名稱微電網電化學儲能元件開發
年度2017
類別研討會
摘要
關鍵字